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Author:

Zheng, Ting (Zheng, Ting.) | Wu, Jiagang (Wu, Jiagang.) | Cheng, Xiaojing (Cheng, Xiaojing.) | Wang, Xiaopeng (Wang, Xiaopeng.) | Zhang, Binyu (Zhang, Binyu.) | Xiao, Dingquan (Xiao, Dingquan.) | Zhu, Jianguo (Zhu, Jianguo.) | Loub, Xiaojie (Loub, Xiaojie.) | Wang, Xiangjian (Wang, Xiangjian.)

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SCIE EI Scopus

Abstract:

In this work, we elucidate the influence of Bi0.5Li0.5ZrO3(BLZ) content on the phase structure, microstructure, and electrical properties of (1 - x)K0.40Na0.60Nb0.965Sb0.O-035(3)-xBi(0.5)Li(0.5)ZrO(3) lead-free ceramics. We simultaneously achieved a giant d(33) and a high T-c in this material system. The coexistence of rhombohedral and tetragonal phases is responsible for such a large d(33) in the ceramics with BLZ contents (x) ranging from 0.025 to 0.035. Doping with BLZ not only induces the formation of the phase boundary, but also maintains a high T-c. The ceramic with x = 0.03 shows an enhanced piezoelectric behaviour (d(33) similar to 400 pC N-1 and K-p similar to 0.47) together with a high T-c of 292 degrees C. A good temperature stability for ferroelectricity and piezoelectricity is also observed in these ceramics. This study is the first time that such a good comprehensive performance has been obtained in potassium-sodium niobate materials. We believe that this type of material system possessing giant-d(33) and high-T-c is a promising candidate for use in high-temperature piezoelectric devices.

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Author Community:

  • [ 1 ] [Zheng, Ting; Wu, Jiagang; Cheng, Xiaojing; Wang, Xiaopeng; Zhang, Binyu; Xiao, Dingquan; Zhu, Jianguo] Sichuan Univ, Dept Mat Sci, Chengdu 610064, Peoples R China
  • [ 2 ] [Loub, Xiaojie; Wang, Xiangjian] Xi An Jiao Tong Univ, Frontier Inst Sci & Technol, Multi Disciplinary Mat Res Ctr, Xian 710049, Peoples R China
  • [ 3 ] [Loub, Xiaojie; Wang, Xiangjian] Xi An Jiao Tong Univ, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China

Reprint Author's Address:

  • Sichuan Univ, Dept Mat Sci, Chengdu 610064, Peoples R China.

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Source :

DALTON TRANSACTIONS

ISSN: 1477-9226

Year: 2014

Issue: 30

Volume: 43

Page: 11759-11766

4 . 1 9 7

JCR@2014

4 . 3 9 0

JCR@2020

ESI Discipline: CHEMISTRY;

ESI HC Threshold:221

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 39

SCOPUS Cited Count: 41

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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