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Author:

Wang, Xiaobing (Wang, Xiaobing.) | Hu, Jiangjiang (Hu, Jiangjiang.) | Su, Yichang (Su, Yichang.) | Hao, Jin (Hao, Jin.) | Liu, Fanggang (Liu, Fanggang.) | Han, Shuang (Han, Shuang.) | An, Jian (An, Jian.) | Lian, Jianshe (Lian, Jianshe.)

Indexed by:

SCIE

Abstract:

A novel Ni foam-Ni3S2@Ni(OH)(2)-graphene sandwich- structured electrode (NF-NN-G) with high areal mass loading (8.33 mgcm(-2)) has been developed by sulfidation and hydrolysis reactions. The conductivity of Ni3S2 and Ni(OH)(2) were both improved. The upper layer of Ni(OH)(2), covered with a thin graphene film, is formed in situ from the surface of the lower layer of Ni3S2, whereas the Ni3S2 grown on Ni foam substrate mainly acts as a rough support bridging the Ni(OH)(2) and Ni foam. The graphene stabilized the Ni(OH)(2) and the electrochemical properties were effectively enhanced. The as-synthesized NF-NN-G-5mg electrode shows a high specific capacitance (2258 Fg(-1) at 1 Ag-1 or 18.81 F cm(-2) at 8.33 mAcm(-2)) and an outstanding rate property (1010 Fg(-1) at 20 Ag-1 or 8.413 Fcm(-2) at 166.6 mAcm(-2)). This result is around double the capacitance achieved in previous research on Ni3S2@ Ni(OH)(2)/3 DGN composites (3DGN= three-dimensional graphene network). In addition, the asfabricated NF-NN-G-5mg composite electrode has an excellent cycle life with no capacitance loss after 3000 cycles, indicating a potential application as an efficient electrode.

Keyword:

conducting materials conductivity electrochemical properties graphene sandwich architecture supercapacitor

Author Community:

  • [ 1 ] [Wang, Xiaobing; Hu, Jiangjiang; Su, Yichang; Hao, Jin; Liu, Fanggang; Han, Shuang; An, Jian; Lian, Jianshe] Jilin Univ, Minist Educ, Key Lab Automobile Mat, Dept Mat Sci & Engn, Changchun 130022, Peoples R China
  • [ 2 ] [Hu, Jiangjiang] Northwest Inst Nonferrous Met Res, Adv Mat Res, Xian 710049, Peoples R China

Reprint Author's Address:

  • Jilin Univ, Minist Educ, Key Lab Automobile Mat, Dept Mat Sci & Engn, Changchun 130022, Peoples R China.

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Source :

CHEMISTRY-A EUROPEAN JOURNAL

ISSN: 0947-6539

Year: 2017

Issue: 17

Volume: 23

Page: 4128-4136

5 . 1 6

JCR@2017

5 . 2 3 6

JCR@2020

ESI Discipline: CHEMISTRY;

ESI HC Threshold:160

JCR Journal Grade:1

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 33

SCOPUS Cited Count: 12

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

Affiliated Colleges:

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