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Novel High-Rate Performance of Dual Carbon-Coated Li3V2(PO4)(3) Materials Used in an Aqueous Electrolyte SCIE
期刊论文 | 2019 , 58 (2) , 790-797 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
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Lithium vanadium phosphate (Li3V2(PO4)(3)) coated with dual carbon-citric acid and polyvinylpyrrolidone (PVP), are used as the cathode materials for the novel aqueous rechargeable lithium-ion batteries (ARLBs). Li+ diffusion coefficient of Li3V2(PO4)(3)/C (LVP/C) is first calculated and reported for the ARLBs. The primary discharge specific capacities of LVP/C reaches 125.8 mA h g(-1) (1 C), 122.7 mA h g(-1) (2 C), 113.6 mA h g(-1) (5 C) and 101.6 mA h g(-1) (10 C), respectively. Particularly, at 50 C (equivalent to an ampere density of 6.6 A g(-1)), the capacity has almost no decrease after 300 cycles. At a novel 100 C (13.2 A g(-1)), 94.9% of capacity retention is achieved after 1000 cycles, and the Coulombic efficiency approximates equal to 100%. Lithium vanadium phosphate with a NASCION structure is regarded as the great promising candidate material for power batteries owing to its high safety, superior structural stability, and excellent electrochemical performance.

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GB/T 7714 Ding, Meng , Zhao, Mingshu , Gong, Huilin et al. Novel High-Rate Performance of Dual Carbon-Coated Li3V2(PO4)(3) Materials Used in an Aqueous Electrolyte [J]. | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH , 2019 , 58 (2) : 790-797 .
MLA Ding, Meng et al. "Novel High-Rate Performance of Dual Carbon-Coated Li3V2(PO4)(3) Materials Used in an Aqueous Electrolyte" . | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 58 . 2 (2019) : 790-797 .
APA Ding, Meng , Zhao, Mingshu , Gong, Huilin , Zheng, Qingyang , Song, Xiaoping . Novel High-Rate Performance of Dual Carbon-Coated Li3V2(PO4)(3) Materials Used in an Aqueous Electrolyte . | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH , 2019 , 58 (2) , 790-797 .
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Selective synthesis of CuO/C nanocomposites and porous CuO based on polyacrylic acid hydrogel system as high-performance anode for lithium-ion batteries Scopus SCIE
期刊论文 | 2019 , 518 , 1-7 | Chemical Physics
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© 2018 Elsevier B.V. CuO/C nanocomposites and porous CuO were selectively synthesized by a facile, low-cost and large-scale synthesis method based on polyacrylic acid hydrogel system. As the anode materials for lithium-ion batteries, the capacity of porous CuO is higher than CuO/C nanocomposites, while gradually decreases after 40 cycles due to the lack of supporting matrix. In CuO/C nanocomposites, CuO nanoparticles are uniformly embedded in the three-dimensional carbon matrix, which can buffer the large volume change, suppress the particle pulverization, and prevent the particle agglomeration of CuO nanoparticles. The capacity of CuO/C nanocomposites maintains at about 690 mAh g−1 till 200th cycle.

Keyword :

Anodes Copper oxide Hydrogel Lithium ion batteries Nanocomposites

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GB/T 7714 Wang, Fei , Cheng, Danfei , Cheng, Tingting et al. Selective synthesis of CuO/C nanocomposites and porous CuO based on polyacrylic acid hydrogel system as high-performance anode for lithium-ion batteries [J]. | Chemical Physics , 2019 , 518 : 1-7 .
MLA Wang, Fei et al. "Selective synthesis of CuO/C nanocomposites and porous CuO based on polyacrylic acid hydrogel system as high-performance anode for lithium-ion batteries" . | Chemical Physics 518 (2019) : 1-7 .
APA Wang, Fei , Cheng, Danfei , Cheng, Tingting , Zong, Jingui , Long, Yixuan , Zhao, Mingshu et al. Selective synthesis of CuO/C nanocomposites and porous CuO based on polyacrylic acid hydrogel system as high-performance anode for lithium-ion batteries . | Chemical Physics , 2019 , 518 , 1-7 .
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Excellent cycling stabilities of a novel calliandra-like Co3O4acted as anode materials for the lithium-ion battery EI Scopus CSSCI-E SCIE
期刊论文 | 2018 , 17 , 311-317 | Journal of Energy Storage
WoS CC Cited Count: 1 SCOPUS Cited Count: 2
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Herein, a hierarchical calliandra-like Co3O4is successfully synthesized via a simple carbon sphere and hydroxypropyl cellulose assisted hydrothermal process. X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM) characteristics results indicate that the hierarchical Co3O4spheres are 3–6 μm in diameter and belong to spinel structure. Each Co3O4sphere is consisted of radially oriented nanocystals accumulated nanorods building blocks. The formation mechanism for this structure maybe ascribed to the collaboration effect of carbon sphere and hydroxypropyl cellulose, which act as hard template and dispersion stabilizer respectively. The calliandra-like Co3O4particles exhibit satisfied electrochemical performance with high specific capacities and good rate capabilities, especially superior cycling stability when used as anode active materials in the lithium-ion batteries, which release an initial discharge capacity of 1139.42 mA h g−1at 200 mA g−1, and maintain a reversible capacity of 734.64 mA h g−1after 500 cycles. © 2018 Elsevier Ltd

Keyword :

Calliandra-like Co3O4 Cycling stability Growth mechanisms Hydroxypropyl cellulose Lithium-ion battery anodes

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GB/T 7714 Liang, Miaomiao , Zhao, Mingshu , Wang, Haiyang et al. Excellent cycling stabilities of a novel calliandra-like Co3O4acted as anode materials for the lithium-ion battery [J]. | Journal of Energy Storage , 2018 , 17 : 311-317 .
MLA Liang, Miaomiao et al. "Excellent cycling stabilities of a novel calliandra-like Co3O4acted as anode materials for the lithium-ion battery" . | Journal of Energy Storage 17 (2018) : 311-317 .
APA Liang, Miaomiao , Zhao, Mingshu , Wang, Haiyang , Wang, Fei , Song, Xiaoping . Excellent cycling stabilities of a novel calliandra-like Co3O4acted as anode materials for the lithium-ion battery . | Journal of Energy Storage , 2018 , 17 , 311-317 .
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Enhanced cycling stability of hierarchical NiCo2S4@Ni(OH)(2)@PPy core-shell nanotube arrays for aqueous asymmetric supercapacitors EI SCIE Scopus
期刊论文 | 2018 , 6 (6) , 2482-2493 | JOURNAL OF MATERIALS CHEMISTRY A
WoS CC Cited Count: 29 SCOPUS Cited Count: 37
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In this article, a novel electrode of NiCo2S4@Ni(OH)(2)@polypyrrole nanotube arrays supported on nickel foam is fabricated through a facile method. Due to the superior electronic conductivity of the shell material polypyrrole (PPy) and the high pseudocapacitance of Ni(OH)(2) together with the short ion transport pathway of NiCo2S4 nanotube arrays, the obtained core-shell NiCo2S4@Ni(OH)(2)@PPy shows an enhanced pseudocapacitive performance of about 9.1125 F cm(-2) at a current density of 5 mA cm(-2), which is nearly three times higher than that of the pristine NiCo2S4 sample (3.1875 F cm(-2)). The kinetic analysis reveals the diffusion controlled faradaic characteristic of NiCo2S4@Ni(OH)(2)@PPy (43.57% capacitive contribution). Moreover, an asymmetric supercapacitor is successfully assembled with NiCo2S4@Ni(OH)(2)@PPy as the positive electrode and active carbon (AC) as the negative electrode. The NiCo2S4@Ni(OH)(2)@PPy// AC device exhibits a relatively high energy density of 34.67 W h kg(-1) at a power density of 120.127 W kg(-1) and excellent cycling performance (about 98.87% capacitance retention over 30 000 cycles). The results show that the NiCo2S4@Ni(OH)(2)@PPy core-shell nanotube array is a promising electrode material for high performance super-capacitor applications.

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GB/T 7714 Liang, Miaomiao , Zhao, Mingshu , Wang, Haiyang et al. Enhanced cycling stability of hierarchical NiCo2S4@Ni(OH)(2)@PPy core-shell nanotube arrays for aqueous asymmetric supercapacitors [J]. | JOURNAL OF MATERIALS CHEMISTRY A , 2018 , 6 (6) : 2482-2493 .
MLA Liang, Miaomiao et al. "Enhanced cycling stability of hierarchical NiCo2S4@Ni(OH)(2)@PPy core-shell nanotube arrays for aqueous asymmetric supercapacitors" . | JOURNAL OF MATERIALS CHEMISTRY A 6 . 6 (2018) : 2482-2493 .
APA Liang, Miaomiao , Zhao, Mingshu , Wang, Haiyang , Shen, Junfang , Song, Xiaoping . Enhanced cycling stability of hierarchical NiCo2S4@Ni(OH)(2)@PPy core-shell nanotube arrays for aqueous asymmetric supercapacitors . | JOURNAL OF MATERIALS CHEMISTRY A , 2018 , 6 (6) , 2482-2493 .
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Spin reorientation and magnetoelastic properties of ferromagnetic Tb1-xNdxCo2 systems with a morphotropic phase boundary SCIE Scopus
期刊论文 | 2018 , 97 (10) | PHYSICAL REVIEW B
WoS CC Cited Count: 1 SCOPUS Cited Count: 1
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The spin reorientation (SR) and magnetoelastic properties of pseudobinary ferromagnetic Tb1-xNdxCo2 (0 <= x <= 1.0) systems involving a morphotropic phase boundary (MPB) were studied by high-resolution synchrotron x-ray diffraction (XRD), magnetization, and magnetostriction measurements. The easy magnetization direction of the Laves phase lies along the < 111 > axis with x < 0.65, whereas it lies along the < 100 > axis for x > 0.65 below Curie temperature (T-C). The temperature-dependent magnetization curves showed SR; this can be explained by a two-sublattice model. Based on the synchrotron (XRD) and magnetization measurements, the SR phase diagram for a MPB composition of Tb0.35Nd0.65Co2 was obtained. Contrary to previously reported ferromagnetic systems involving MPB, the MPB composition of Tb0.35Nd0.65Co2 exhibits a low saturation magnetization (M-S), indicating a compensation of the Tb and Nd magnetic moments at MPB. The anisotropic magnetostriction (lambda(S)) first decreased until x = 0.8 and then continuously increased in the negative direction with further increase of Nd concentration. The decrease in magnetostriction can be attributed to the decrease of spontaneous magnetostriction lambda(111) and increase of lambda(100) with opposite sign to lambda(111). This paper indicates an anomalous type of MPB in the ferromagnetic Tb1-xNdxCo2 system and provides an active way to design novel functional materials with exotic properties.

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GB/T 7714 Murtaza, Adil , Yang, Sen , Chang, Tieyan et al. Spin reorientation and magnetoelastic properties of ferromagnetic Tb1-xNdxCo2 systems with a morphotropic phase boundary [J]. | PHYSICAL REVIEW B , 2018 , 97 (10) .
MLA Murtaza, Adil et al. "Spin reorientation and magnetoelastic properties of ferromagnetic Tb1-xNdxCo2 systems with a morphotropic phase boundary" . | PHYSICAL REVIEW B 97 . 10 (2018) .
APA Murtaza, Adil , Yang, Sen , Chang, Tieyan , Ghani, Awais , Khan, Muhammad Tahir , Zhang, Rui et al. Spin reorientation and magnetoelastic properties of ferromagnetic Tb1-xNdxCo2 systems with a morphotropic phase boundary . | PHYSICAL REVIEW B , 2018 , 97 (10) .
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Zero-thermal-hysteresis magnetocaloric effect induced by magnetic transition at a morphotropic phase boundary in Heusler Ni50Mn36Sb14-xInx alloys SCIE PubMed Scopus
期刊论文 | 2018 , 20 (27) , 18484-18490 | PHYSICAL CHEMISTRY CHEMICAL PHYSICS
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With the development of magnetic refrigerant technology, magnetic substances with a large magnetocaloric effect (MCE) and nearly zero thermal hysteresis are desired. Although Ni-Mn based Heusler alloys have been found to produce large MCEs and have attracted increasing attention recently, the occurrence of thermal hysteresis accompanying MCE due to the nature of first-order phase transition limits its applications with magnetic refrigeration. Up to now, an effective theory or method to eliminate this thermal hysteresis is still lacking. Here, we propose to utilize the feature of magnetic transition at the morphotropic phase boundary (MPB) to eliminate thermal hysteresis and thus design a MPB-involved phase diagram in Heusler alloys of Ni50Mn36Sb14-xInx (x = 0-14). As theoretically expected, the magnetic transition at MPB really yields a MCE with a negligible thermal hysteresis (similar to 0 K) and the refrigerant capacity arrives at a maximum value of 108.2 J kg(-1) at the composition of x = 9. Our findings provide an effective way to design large MCE materials with zero thermal hysteresis.

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GB/T 7714 Zhang, Yin , Wang, Jieqiong , Ke, Xiaoqin et al. Zero-thermal-hysteresis magnetocaloric effect induced by magnetic transition at a morphotropic phase boundary in Heusler Ni50Mn36Sb14-xInx alloys [J]. | PHYSICAL CHEMISTRY CHEMICAL PHYSICS , 2018 , 20 (27) : 18484-18490 .
MLA Zhang, Yin et al. "Zero-thermal-hysteresis magnetocaloric effect induced by magnetic transition at a morphotropic phase boundary in Heusler Ni50Mn36Sb14-xInx alloys" . | PHYSICAL CHEMISTRY CHEMICAL PHYSICS 20 . 27 (2018) : 18484-18490 .
APA Zhang, Yin , Wang, Jieqiong , Ke, Xiaoqin , Chang, Tieyan , Tian, Fanghua , Zhou, Chao et al. Zero-thermal-hysteresis magnetocaloric effect induced by magnetic transition at a morphotropic phase boundary in Heusler Ni50Mn36Sb14-xInx alloys . | PHYSICAL CHEMISTRY CHEMICAL PHYSICS , 2018 , 20 (27) , 18484-18490 .
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Electric modulation of conduction in multiferroic Ni-doped GaFeO3 ceramics EI SCIE Scopus
期刊论文 | 2018 , 51 (22) | JOURNAL OF PHYSICS D-APPLIED PHYSICS
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In this work, the effects of Ni substitution on the electrical leakage and multiferroic properties of GaFeO3 were examined. Structural analysis of grown ceramics using x-ray diffraction and Raman shows that all ceramics have pure phases with an orthorhombic structure and Pc2(1)n space group. Ni substitutions slightly modify lattice parameters and induce lattice distortion within the same crystalline structure. It is observed that with increasing Ni-content up to 0.10, the magnetic transition temperature (T-C) increases from 196 K to 407 K. Ni-doped samples showed better ferroelectric properties and a drastic reduction in leakage current (similar to three orders of magnitude) at room temperature. Enhanced characteristics behavior is observed for 10% Ni substitution (GaFe0.9Ni0.1O3) and higher substitution leads to deterioration of properties with a larger leakage current. It is proposed that the role of Ni substitution can reduce hopping between Fe+3 and Fe+2 as well as suppressing the oxygen vacancies. This work would open new possibilities for integrating polycrystalline GaFeO3 at room temperature for magnetoelectric applications.

Keyword :

polarization magnetization leakage current

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GB/T 7714 Ghani, Awais , Yang, Sen , Rajput, S. S. et al. Electric modulation of conduction in multiferroic Ni-doped GaFeO3 ceramics [J]. | JOURNAL OF PHYSICS D-APPLIED PHYSICS , 2018 , 51 (22) .
MLA Ghani, Awais et al. "Electric modulation of conduction in multiferroic Ni-doped GaFeO3 ceramics" . | JOURNAL OF PHYSICS D-APPLIED PHYSICS 51 . 22 (2018) .
APA Ghani, Awais , Yang, Sen , Rajput, S. S. , Ahmed, S. , Murtaza, Adil , Zhou, Chao et al. Electric modulation of conduction in multiferroic Ni-doped GaFeO3 ceramics . | JOURNAL OF PHYSICS D-APPLIED PHYSICS , 2018 , 51 (22) .
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Premartensite serving as an intermediary state between strain glass and martensite in ferromagnetic Ni-Fe-Mn-Ga EI SCIE Scopus
期刊论文 | 2018 , 152 , 102-109 | MATERIALS & DESIGN
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Previous investigations indicate that the two intrinsically different states, i.e, strain glass and premartensite in ferromagnetic Ni-Mn-Ga based system share some similarities in their transforming properties, such as nano domain structure, elastic anomaly and temperature-induced transition to martensite. This indicates that the two states are possibly related with each other. However, the relationship between them is unclear so far. To explore this problem, we investigated the transforming behaviors of the ferromagnetic Ni-55,,FexMn120Ga25 (x 4-14) sysLem.11. was found that the transforming route of this system changes greatly with increasing Fe conlent. We also observed that the strain glass transforms info premartensilic stale upon cooling, which is called spontaneous strain glass to premartensite transition. The local structure of strain glass is similar to thaL of premartensite. Moreover, a strain glass phase diagram of the Ni-Fe-Mn-Ga system was constructed, which reveals that the premartensite serves as an intermediary slate between strain glass and martensite. With increasing Fe doping, the system changes from the marlensile (long-range-ordered sfrain stale with large spontaneous sir-din) into Lhe premartensite (long-range ordered strain stale with small spontaneous strain) al first, and then the strain glass (short-range-ordered strain stale with small local strain) is derived from pi-mai-tensile by further doping Fe. (C) 2018 Elsevier Ltd. All rights reserved.

Keyword :

Martensitic transformation Premartensite Strain glass Ferromagnetic shape memory alloy Martensite

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GB/T 7714 Wang, Yu , Huang, Chonghui , Wu, Haijun et al. Premartensite serving as an intermediary state between strain glass and martensite in ferromagnetic Ni-Fe-Mn-Ga [J]. | MATERIALS & DESIGN , 2018 , 152 : 102-109 .
MLA Wang, Yu et al. "Premartensite serving as an intermediary state between strain glass and martensite in ferromagnetic Ni-Fe-Mn-Ga" . | MATERIALS & DESIGN 152 (2018) : 102-109 .
APA Wang, Yu , Huang, Chonghui , Wu, Haijun , Gao, Jinghui , Yang, Sen , Song, Xiaoping et al. Premartensite serving as an intermediary state between strain glass and martensite in ferromagnetic Ni-Fe-Mn-Ga . | MATERIALS & DESIGN , 2018 , 152 , 102-109 .
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Combination of conventional elastocaloric and magnetocaloric effects in a Co37Ni35Al28 ferromagnetic shape memory alloy EI SCIE Scopus
期刊论文 | 2018 , 146 , 182-186 | SCRIPTA MATERIALIA
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The elastocaloric and magnetocaloric effects in a polycrystalline ferromagnetic shape memory alloy Co37Ni35Al28 are investigated. The alloy shows conventional elastocaloric effect with entropy change of 5.05 J kg(-1) K-1 under 350 MPa. The temperature change of its elastocaloric effect is over 1 K within a working temperature range of 80K covering ambient temperature. Moreover, the alloy also shows conventional magnetocaloric effect. The conventional elastocaloric and magnetocaloric effects of the alloy possess the same sign of entropy change and temperature change, the simultaneous use of multiple caloric effects can be achieved by applying stress and magnetic field, which improves its overall refrigeration capability. (C) 2017 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Keyword :

Martensitic transformation Ferromagnetic transition Ferromagnetic shape memory alloy Elastocaloric effect Magnetocaloric effect

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GB/T 7714 Khan, Muhammad Tahir , Wang, Yu , Wang, Cong et al. Combination of conventional elastocaloric and magnetocaloric effects in a Co37Ni35Al28 ferromagnetic shape memory alloy [J]. | SCRIPTA MATERIALIA , 2018 , 146 : 182-186 .
MLA Khan, Muhammad Tahir et al. "Combination of conventional elastocaloric and magnetocaloric effects in a Co37Ni35Al28 ferromagnetic shape memory alloy" . | SCRIPTA MATERIALIA 146 (2018) : 182-186 .
APA Khan, Muhammad Tahir , Wang, Yu , Wang, Cong , Liao, Xiaoqi , Yang, Sen , Song, Xiaoping et al. Combination of conventional elastocaloric and magnetocaloric effects in a Co37Ni35Al28 ferromagnetic shape memory alloy . | SCRIPTA MATERIALIA , 2018 , 146 , 182-186 .
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Temperature dependent magnetization and coercivity in morphotropic phase boundary involved ferromagnetic Tb1-xGdxFe2 system EI SCIE Scopus
期刊论文 | 2018 , 217 , 278-284 | MATERIALS CHEMISTRY AND PHYSICS
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Morphotropic phase boundary (MPB) refers to a transition region separating two ferromagnetic phases having different crystallographic symmetries in a ferromagnetic system. In the present study, magnetization and coercivity of the MPB involved ferromagnetic Tb1-xGdxFe2 system have been measured at selected temperatures between 5 and 300 K. The saturation magnetization M-S of the Tb1-xGdxFe2 system varies with Gd concentration exhibiting minimum value at MPB composition x = 0.9 at all temperatures. Calculated magnetic moments of rare earth (RE) elements are lower than those of their corresponding free ions, which can be attributed to the crystal field effect (CFE). The magnetic anisotropy K decreases with increasing Gd concentration and anisotropy compensation has been observed at an MPB composition with x = 0.9. The coercivity H-C of the Tb1-xGdxFe2 system was found to decrease with increasing the Gd concentration. Furthermore, H-C exhibits a large value at low temperature and decays exponentially with increasing temperature. The observed temperature dependence of the H-C can be explained by domain wall pinning, as a high K of rare earth elements (RE) at low temperatures causes a prominent pinning effect at 5 K. Our results shed light on magnetization, magnetic anisotropy and coercivity mechanisms in MPB involved ferromagnetic systems and provides an effective way to design novel functional materials.

Keyword :

Domain wall pinning Magnetic anisotropy Morphotropic phase boundary Crystal field effect Intrinsic coercivity

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GB/T 7714 Murtaza, Adil , Yang, Sen , Khan, Muhammad Tahir et al. Temperature dependent magnetization and coercivity in morphotropic phase boundary involved ferromagnetic Tb1-xGdxFe2 system [J]. | MATERIALS CHEMISTRY AND PHYSICS , 2018 , 217 : 278-284 .
MLA Murtaza, Adil et al. "Temperature dependent magnetization and coercivity in morphotropic phase boundary involved ferromagnetic Tb1-xGdxFe2 system" . | MATERIALS CHEMISTRY AND PHYSICS 217 (2018) : 278-284 .
APA Murtaza, Adil , Yang, Sen , Khan, Muhammad Tahir , Ghani, Awais , Zhou, Chao , Song, Xiaoping . Temperature dependent magnetization and coercivity in morphotropic phase boundary involved ferromagnetic Tb1-xGdxFe2 system . | MATERIALS CHEMISTRY AND PHYSICS , 2018 , 217 , 278-284 .
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