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Influence of rare earth on the electrical properties and microstructure of barium titanate ceramics

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Author:

Yang Wenhu (Yang Wenhu.) | Pu Yongping (Pu Yongping.) | Chen Shoutian (Chen Shoutian.)

Indexed by:

CPCI-S Scopus EI

Abstract:

The ceramic samples of BaTiO3+1/2xLn(2)O(3)+2mol%TiO2 (0.001 <= x <= 0.01) were prepared, where Ln is Y, Dy, Ho, Er or Y. The influence of rare earth on the resistivity and microstructure of the samples was investigated by the means of XRD, SEM and electric properties testing. The results showed that the resistivity of La-doped sample decreases when x= 0.003 compared with the undoped sample. However, the range of dopant concentration with Dy, He, Er or Y for semiconducting samples is wider, especially for Y-doping. Minimum resistivity at room temperature was observed when x=0.003, which is named after the critical concentration. The experimental results indicated that below the critical concentration of Dy, Ho, Er or Y, the substitution took place in the barium sublattice with electronic compensation, and the rare earth ions began to substitute for titanium gradually above the critical concentration. For Ho-doped BaTiO3 ceramic, the resistivity jump (PTCR effect) near the Curie temperature was the highest in the case of x=0.003. Fine-grained structure of the sample doped with 0.6mol% Dy led to the increase of breakdown field strength and dielectric constant of ceramic samples.

Keyword:

barium titanate electrical properties microstructure rare earth

Author Community:

  • [ 1 ] [Yang Wenhu; Pu Yongping] Shaanxi Univ Sci & Technol, Sch Mat Sci & Engn, Xian 710021, Peoples R China
  • [ 2 ] [Chen Shoutian] Xi An Jiao Tong Univ, State Key Lab Elect Insulat Power Equipment, Xian 710049, Peoples R China

Reprint Author's Address:

  • Shaanxi Univ Sci & Technol, Sch Mat Sci & Engn, Xian 710021, Peoples R China.

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Source :

HIGH-PERFORMANCE CERAMICS V, PTS 1 AND 2

ISSN: 1013-9826

Year: 2008

Volume: 368-372

Page: 465-+

Language: English

0 . 2 2 4

JCR@2005

JCR Journal Grade:3

Cited Count:

WoS CC Cited Count: 0

30 Days PV: 5

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