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Author:

Liu, Yu (Liu, Yu.) | Yi, Chunhai (Yi, Chunhai.) | Hu, Jiayang (Hu, Jiayang.) | Yang, Bolun (Yang, Bolun.) (Scholars:杨伯伦)

Indexed by:

CPCI-S EI Scopus

Abstract:

A new approach was proposed to remove sulfuric compounds from fluid catalytic cracking (FCC) gasoline by combining an alkylation desulfurization catalytic distillation (ADCD) column with a hydrodesulfurization catalytic distillation (HDS-CD) column. In the ADCD column, isobutylene (IB) and 3-methylthiophene (3MT) were designated as the model compounds for olefin and sulfide, respectively; NKC-9 cation exchange resin was used as the catalyst. In the BIDS-CD column, dibenzothiophene (DBT) was chosen as the model sulfides; Nickel phosphide supported on the TiO2-Al2O3 composite oxide prepared by our laboratory were designated as the HDS catalyst. Simulations for these two CD columns were carried out by RADFRAC module of Aspen Plus. The optimization results revealed that the ADCD column had an alkylation selectivity of 96%, and the sulfur content in the overhead stream was less than 8 mu g/g. The simulation results of the HDS-CD process showed that the sulfide in the bottom stream of ADCD column can be removed practically by 100% and the clean oil stream from the bottom of HDS-CD column has hardly any sulfur.

Keyword:

Alkylation Catalytic distillation (CD) Desulfurization Fluid catalytic cracking (FCC) gasoline Hydrodesulfurization (HDS)

Author Community:

  • [ 1 ] [Liu, Yu; Yi, Chunhai; Hu, Jiayang; Yang, Bolun] Xi An Jiao Tong Univ, Dept Chem Engn, State Key Lab Multiphase Flow Power Engn, Xian 710049, Peoples R China

Reprint Author's Address:

  • Xi An Jiao Tong Univ, Dept Chem Engn, State Key Lab Multiphase Flow Power Engn, Xian 710049, Peoples R China.

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Source :

ADVANCES IN CHEMICAL ENGINEERING II, PTS 1-4

ISSN: 1022-6680

Year: 2012

Volume: 550-553

Page: 550-553

Language: English

Cited Count:

WoS CC Cited Count: 2

SCOPUS Cited Count: 3

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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