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Author:

Lim, Kean Long (Lim, Kean Long.) | Liu, Yongning (Liu, Yongning.) | Zhang, Qing-An (Zhang, Qing-An.) | Lin, Kuen-Song (Lin, Kuen-Song.) | Chan, Sammy Lap Ip (Chan, Sammy Lap Ip.)

Indexed by:

CPCI-S SCIE EI Scopus

Abstract:

The cycle stability of La-Mg-Ni based alloys in a gas solid reaction system was investigated in this work. Both partial substitutions of La and Ni by Ce and Al, respectively, improved the cycle stability of La(0.6-x)CexCa1.03Mg1.32Ni(9-y)Aly alloys. Although the addition of Al reduced the hydrogen storage capacity significantly, it is still important to be included in the system for its superior property in improving the cycle life. Hence, two optimized samples with a small addition of Al (y = 0.10) were used to compare with the cycle life of CaNi5 It was found that the Ce and Al added samples have a better hydrogen capacity retention than that of samples without element substitution; and their overall hydrogen storage capacity was still higher than that of CaNis. We also found that heat treatment used in this study did not fully recover the hydrogen storage capability of La-Mg-Ni based alloy to its original storage capacity. A probable reason was the heat treatment used in this study could only recover the degradation caused by the disproportionation to some extent, but the treatment was unable to reverse the degradation caused by decrepitation. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

Keyword:

Capacity degradation Cycle stability improvement Gas-solid reaction Partial substitution

Author Community:

  • [ 1 ] [Lim, Kean Long] Univ Kebangsaan Malaysia, Fuel Cell Inst, Bangi 43600, Selangor De, Malaysia
  • [ 2 ] [Lim, Kean Long; Chan, Sammy Lap Ip] Univ New South Wales, Sch Mat Sci & Engn, Sydney, NSW 2052, Australia
  • [ 3 ] [Liu, Yongning] Xi An Jiao Tong Univ, State Key Lab Mech Behav Mat, Xian 710049, Shaanxi, Peoples R China
  • [ 4 ] [Zhang, Qing-An] Anhui Univ Technol, Sch Mat Sci & Engn, Maanshan 243002, Peoples R China
  • [ 5 ] [Lin, Kuen-Song] Yuan Ze Univ, Dept Chem Engn, Mat Sci Fuel Cell Ctr, Chung Li City 320, Taiwan
  • [ 6 ] [Lim, Kean Long]Univ Kebangsaan Malaysia, Fuel Cell Inst, Bangi 43600, Selangor De, Malaysia
  • [ 7 ] [Lim, Kean Long]Univ New South Wales, Sch Mat Sci & Engn, Sydney, NSW 2052, Australia
  • [ 8 ] [Chan, Sammy Lap Ip]Univ New South Wales, Sch Mat Sci & Engn, Sydney, NSW 2052, Australia
  • [ 9 ] [Liu, Yongning]Xi An Jiao Tong Univ, State Key Lab Mech Behav Mat, Xian 710049, Shaanxi, Peoples R China
  • [ 10 ] [Zhang, Qing-An]Anhui Univ Technol, Sch Mat Sci & Engn, Maanshan 243002, Peoples R China
  • [ 11 ] [Lin, Kuen-Song]Yuan Ze Univ, Dept Chem Engn, Mat Sci Fuel Cell Ctr, Chung Li City 320, Taiwan

Reprint Author's Address:

  • Univ Kebangsaan Malaysia, Fuel Cell Inst, Bangi 43600, Selangor De, Malaysia.; Chan, SLI (reprint author), Univ New South Wales, Sch Mat Sci & Engn, Sydney, NSW 2052, Australia.

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Source :

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

ISSN: 0360-3199

Year: 2017

Publish Date: SEP 14

Issue: 37

Volume: 42

Page: 23737-23745

Language: English

4 . 2 2 9

JCR@2017

5 . 8 1 6

JCR@2020

ESI Discipline: ENGINEERING;

ESI HC Threshold:121

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 13

SCOPUS Cited Count: 17

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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