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The cycle stability of La-Mg-Ni based alloys in a gas solid reaction system was investigated in this work. Both partial substitutions of La and Ni by Ce and Al, respectively, improved the cycle stability of La(0.6-x)CexCa1.03Mg1.32Ni(9-y)Aly alloys. Although the addition of Al reduced the hydrogen storage capacity significantly, it is still important to be included in the system for its superior property in improving the cycle life. Hence, two optimized samples with a small addition of Al (y = 0.10) were used to compare with the cycle life of CaNi5 It was found that the Ce and Al added samples have a better hydrogen capacity retention than that of samples without element substitution; and their overall hydrogen storage capacity was still higher than that of CaNis. We also found that heat treatment used in this study did not fully recover the hydrogen storage capability of La-Mg-Ni based alloy to its original storage capacity. A probable reason was the heat treatment used in this study could only recover the degradation caused by the disproportionation to some extent, but the treatment was unable to reverse the degradation caused by decrepitation. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
ISSN: 0360-3199
Year: 2017
Publish Date: SEP 14
Issue: 37
Volume: 42
Page: 23737-23745
Language: English
4 . 2 2 9
JCR@2017
5 . 8 1 6
JCR@2020
ESI Discipline: ENGINEERING;
ESI HC Threshold:121
JCR Journal Grade:2
CAS Journal Grade:3
Cited Count:
WoS CC Cited Count: 13
SCOPUS Cited Count: 17
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 5
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