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Abstract:
Nowadays, dielectric materials with high energy storage density play a vital role in the energy storage capacitors. To increase the storage density, 0-3 composite films based on poly(vinylidene fluoride-co-chlorotrifluoroethylene) [P(VDF-CTFE)] and silicon dioxide (SiO2) nanoparticles were prepared by a solution casting method. The composite with 10% SiO2 has a discharged energy density of 2.73 J/cm(3) at 200 MV/m. Furthermore, the local electric field distribution in the P(VDF-CTFE)/SiO2 nanocomposites was analyzed by experiments combined with model simulation. And the relationship of displacement (D) and remanent polarization (P-r) with the current at the applied electric field was investigated. It indicates that during the charging phase, a large positive (+) current value is conducive to obtaining high electrical displacement while in the discharge phase, a small negative current value will be beneficial to achieve a smaller remanent polarization value. Therefore, the addition of low dielectric permittivity fillers (SiO2) contributes to the displacement of the composite at higher electric fields and maintains the P-r in a small range, thus achieving a higher discharged energy density.
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JOURNAL OF ELECTRONIC MATERIALS
ISSN: 0361-5235
Year: 2019
Issue: 12
Volume: 48
Page: 8172-8180
1 . 7 7 4
JCR@2019
1 . 9 3 8
JCR@2020
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:131
JCR Journal Grade:2
CAS Journal Grade:4
Cited Count:
WoS CC Cited Count: 0
SCOPUS Cited Count: 4
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 3