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Author:

Zhang, X. (Zhang, X..) | Yang, Y. (Yang, Y..) | Zhang, X. (Zhang, X..) | Guo, L. (Guo, L..) | Liu, H. (Liu, H..)

Indexed by:

SCIE EI CPCI-S Scopus

Abstract:

Proton exchange membrane fuel cell (PEMFC) experiences inevitably performance decay due to various mechanisms. Among those, carbon corrosion is extremely detrimental. In this study, an accelerated stress test (AST) is conducted to a single cell to mimic the conditions when carbon corrosion occurs. The cell performance is characterized intermittently, and the experiment results show although electrochemical active area (ECA) decreases continuously from beginning-of-life (BOL) due to carbon corrosion at catalyst layer (CL), kinetic degradation is not apparent until AST 3 h. After that, kinetic loss increases progressively, while ohmic loss increases continuously. However, due to decrease of water generation under voltage-controlled condition, or enhancement of water removal by phase change induced flow (PCI) under current-controlled condition, the mass transport is slightly improved at later period of AST. To confirm such variation of mass transport loss, cell performance and EIS are measured at reduced air relative humidity (RHc) and reduced air flow rate. Both cell performance and EIS results show that in a degraded fuel cell, reduced air RHc and higher air flow rate are beneficial to cell performance. Hence, more sophisticated water management strategies for PEMFCs is recommended for different periods in their lifetime for a fuel cell stack.

Keyword:

Accelerated Stress Test Carbon Corrosion Degradation PEMFC Proton Exchange Membrane Fuel Cell

Author Community:

  • [ 1 ] [Zhang, X.; Zhang, X.; Liu, H.] Univ Miami, Clean Energy Res Inst, Dept Mech & Aerosp Engn, Coral Gables, FL 33146 USA
  • [ 2 ] [Zhang, X.; Yang, Y.; Guo, L.] Xi An Jiao Tong Univ, State Key Lab Multiphase Flow Power Engn, Int Res Ctr Renewable Energy, Xian 710049, Shaanxi, Peoples R China
  • [ 3 ] [Yang, Y.] Xidian Univ, Minist Educ, Key Lab Elect Equipment Struct Design, Xian 710071, Shaanxi, Peoples R China
  • [ 4 ] [Zhang, X.]Univ Miami, Clean Energy Res Inst, Dept Mech & Aerosp Engn, Coral Gables, FL 33146 USA
  • [ 5 ] [Zhang, X.]Univ Miami, Clean Energy Res Inst, Dept Mech & Aerosp Engn, Coral Gables, FL 33146 USA
  • [ 6 ] [Liu, H.]Univ Miami, Clean Energy Res Inst, Dept Mech & Aerosp Engn, Coral Gables, FL 33146 USA
  • [ 7 ] [Zhang, X.]Xi An Jiao Tong Univ, State Key Lab Multiphase Flow Power Engn, Int Res Ctr Renewable Energy, Xian 710049, Shaanxi, Peoples R China
  • [ 8 ] [Yang, Y.]Xi An Jiao Tong Univ, State Key Lab Multiphase Flow Power Engn, Int Res Ctr Renewable Energy, Xian 710049, Shaanxi, Peoples R China
  • [ 9 ] [Guo, L.]Xi An Jiao Tong Univ, State Key Lab Multiphase Flow Power Engn, Int Res Ctr Renewable Energy, Xian 710049, Shaanxi, Peoples R China
  • [ 10 ] [Yang, Y.]Xidian Univ, Minist Educ, Key Lab Elect Equipment Struct Design, Xian 710071, Shaanxi, Peoples R China

Reprint Author's Address:

  • [Guo, L.]International Research Center for Renewable Energy, State Key Laboratory of Multiphase Flow in Power Engineering, Xi'an Jiaotong University, Xi'an; Shaanxi; 710049, China;;

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Source :

FUEL CELLS

ISSN: 1615-6846

Year: 2019

Issue: 2

Volume: 19

Page: 160-168

1 . 8 7 6

JCR@2019

2 . 2 5 0

JCR@2020

ESI Discipline: CHEMISTRY;

ESI HC Threshold:104

JCR Journal Grade:2

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 7

SCOPUS Cited Count: 22

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 11

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