To　obtain　durable　adhesive,　highly　hydrophobic,　and　thermostable　coatings,　novel　fluorinated　glycidyl　copolymers　grafted　on　SiO2　nanoparticles　were　prepared　by　SiO2-Br　initiating　covalent　adhesion　of　glycidyl　methacrylate　(GMA)　and　low　surface　free　energy　of　dodecafluoroheptyl　methacrylate　(12FMA)　via　surface　initiated　atom　transfer　radical　polymerization.　In　tetrahydrofuran　solution,　the　obtained　random-structured　SiO2-g-(PGMA-co-P12FMA)　behaves　with　120　±　10　nm　core-shell　morphology　as　SiO2-core　(110　±　10　nm)　and　(PGMA-co-P12FMA)　shell　(8　±　2　nm).　The　films　cast　by　these　core-shell　particles　reveal　stronger　hydrophobic　surfaces　(SAC　=　114-119°),　higher　resistance　to　water　absorption　(Δm　=　2478　ng·Hz-1·cm-2),　and　harder　viscoelasticity　(ΔD/Δf　=　-0.379)　compared　to　the　SiO2-g-PGMA　film　(SAC　=　90°,　Δm　=　6153.7　ng·Hz-1·cm-2,　and　ΔD/Δf　=　-0.271)　due　to　the　accumulated　fluorine-rich　surface　and　increased　surface　roughness.　The　introduction　of　antiaging　P12FMA　obviously　improves　the　durability　of　adhesive　strength　of　SiO2-g-(PGMA-co-P12FMA)　(1.82　MPa)　compared　with　that　of　SiO2-g-PGMA　(decreased　from　1.92　to　1.56　MPa)　during　the　humidity　thermal　aging　cycles.　Meanwhile,　SiO2-g-(PGMA-co-P12FMA)　displays　thermostability　higher　than　that　of　both　SiO2-PGMA　and　PGMA-co-P12FMA,　attributed　to　the　contribution　of　SiO2　and　P12FMA.　Therefore,　it　is　believed　that　SiO2-g-(PGMA-co-P12FMA)　could　be　an　excellent　potential　candidate　for　highly　hydrophobic　and　durable　adhesive　coatings.　©　2018　American　Chemical　Society.