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Author:

Zhao, D. (Zhao, D..) | Wang, M. (Wang, M..) | Kong, T. (Kong, T..) | Shang, Y. (Shang, Y..) | Du, X. (Du, X..) | Guo, L. (Guo, L..) | Shen, S. (Shen, S..)

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Abstract:

The high rate of charge carrier recombination greatly limits the photocatalytic activity of graphitic carbon nitride (g-C3N4). In this contribution, body center cubic indium tin oxide nanoparticles (ITO NPs) as electronic pumps are directly formed on g-C3N4 via a facile one-pot method. The hydrogen production rate of Pt/ITO/g-C3N4 is 3.3 times as high as that of Pt/g-C3N4 under visible light (λ > 420 nm) irradiation. The excellent photocatalytic hydrogen evolution performance should be attributed to the close contact of well-dispersed ITO NPs with g-C3N4 in the prepared ITO/g-C3N4 and in situ formation of Pt onto ITO NPs, leading to accelerated photogenerated electron transfer from g-C3N4 to Pt through ITO pumps for hydrogen generation. In the present work, we successfully demonstrate a high-performance Pt/ITO/g-C3N4 system for visible light hydrogen evolution, and the essential role of ITO NPs as the electronic pumps for efficient photogenerated electron transfer could be informative for designing efficient systems for solar hydrogen generation. © 2018 Elsevier Ltd

Keyword:

Carbon nitride Electron transitions Hydrogen production Light Nitrides Photocatalytic activity Platinum Pumps Solar power generation Tin oxides

Author Community:

  • [ 1 ] [Zhao, D.]International Research Center for Renewable Energy, State Key Laboratory of Multiphase Flow in Power Engineering, Xi'an Jiaotong University, Xi'an; 710049, China
  • [ 2 ] [Wang, M.]International Research Center for Renewable Energy, State Key Laboratory of Multiphase Flow in Power Engineering, Xi'an Jiaotong University, Xi'an; 710049, China
  • [ 3 ] [Kong, T.]College of Chemistry and Chemical Engineering, Xi'an Shiyou University, Xi'an; 710054, China
  • [ 4 ] [Shang, Y.]International Research Center for Renewable Energy, State Key Laboratory of Multiphase Flow in Power Engineering, Xi'an Jiaotong University, Xi'an; 710049, China
  • [ 5 ] [Du, X.]International Research Center for Renewable Energy, State Key Laboratory of Multiphase Flow in Power Engineering, Xi'an Jiaotong University, Xi'an; 710049, China
  • [ 6 ] [Guo, L.]International Research Center for Renewable Energy, State Key Laboratory of Multiphase Flow in Power Engineering, Xi'an Jiaotong University, Xi'an; 710049, China
  • [ 7 ] [Shen, S.]International Research Center for Renewable Energy, State Key Laboratory of Multiphase Flow in Power Engineering, Xi'an Jiaotong University, Xi'an; 710049, China

Reprint Author's Address:

  • [Shen, S.]International Research Center for Renewable Energy, State Key Laboratory of Multiphase Flow in Power Engineering, Xi'an Jiaotong University, Xi'an; 710049, China;;

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Source :

Materials Today Chemistry

Year: 2019

Volume: 11

Page: 296-302

8 . 3 0 1

JCR@2020

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 15

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 13

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