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Abstract:
Non-isothermal differential scanning calorimetry(DSC) method was used to study the curing behavior of Al2O3/epoxy (EP) composites for extra-high voltage gas insulated switchgear (GIS). The DSC curves were subjected to peak separation treatment, and the apparent activation energy of different reaction stages was studied by the equal conversion rate method. According to the Málek criterion, the model type of the curing behavior of Al2O3/EP composites was obtained, and the kinetic parameters of different reaction stages and the curing kinetic equation of the Al2O3/EP composites were obtained. The microstructure of Al2O3/EP composites was observed by SEM, dynamic thermomechanical properties and creep behavior of Al2O3/EP composites were analyzed by dynamic mechanical analysis(DMA), and the long-term creep properties were predicted by time-temperature superposition. The results indicate that DSC heat flow curves are bimodal of Al2O3/EP composites. The apparent activation energies of Al2O3/EP composites at two reaction stages are 35.3 kJ/mol and 48.1 kJ/mol, respectively. The curing behavior of Al2O3/EP composite system at different curing stages can be well described by the Sestak-Berggren model. Al2O3 particles are uniformly dispersed in the resin matrix, and the addition of Al2O3 filler causes cracks to be deflected. The storage modulus (E') of Al2O3/EP composites decreases with increasing temperature, and the peak of loss tangent (tanδ) corresponds to the glass transition temperature (Tg) is 120.03. Creep resistance of Al2O3/EP composites decreases with increase of tensile stress and temperature. The creep rate decreases over time. © 2020, Editorial Office of Acta Materiae Compositae Sinica. All right reserved.
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Acta Materiae Compositae Sinica
ISSN: 1000-3851
Year: 2020
Issue: 3
Volume: 37
Page: 562-572
Cited Count:
WoS CC Cited Count: 0
SCOPUS Cited Count: 5
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 22
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