This　work　concentrated　on　the　fabrication　of　effective　slippery　liquid-infused　porous　surfaces　(SLIPSs)　to　robustly　resist　ice　adhesion　by　using　facile　method　and　smart　composition.　Firstly,　poly(methyl　methacrylate)　(PMMA),　polyhedral　oligomeric　silsesquioxane　end-functionalized　PMMA　(POSS-ef-PMMA)　and　polydimethylsiloxane-blocked　PMMA　(PDMS-b-PMMA)　were　synthesized.　Secondly,　micro-sized　pores　arranged　in　a　three-layer　honeycomb-like　array　at　a　thickness　of　ca.　10　μm　were　elicited　on　each　surface　of　these　three　cast　polymer　films　by　breath-figure　(BF)　method.　After　a　separate　infiltration　of　polydimethylsiloxane　(PDMS),　poly　(hydrogenmethylsiloxane)　(PHMS)　and　hexadecane　(HD)　into　the　porous　matrixes,　typical　SLIPSs　were　formed.　PDMS-b-PMMA　matrix　with　preferential　lipophilicity　towards　PDMS　endowed　the　obtained　SLIPS　with　better　icephobicity.　However,　HD-induced　SLIPSs　performed　the　lowest　sliding　angles　at　6°　for　3　μL　of　water　droplet,　the　lowest　ice　adhesional　strength　ranging　from　40.8–46.3　kPa　and　the　most　robust　anti-icing　properties　of　resisting　more　than　30　icing/de-icing　cycles　without　changing　the　ice　adhesional　strength.　Such　effective　anti-icing　performance　was　ascribed　to　the　better　liquid　nature　of　HD　in　contact　with　water　and　the　solid　nature　of　HD　under　freezing　condition,　which　could　decrease　the　interfacial　friction　and　abrasion　of　HD　against　water　or　ice.　©　2020　Elsevier　B.V.