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Author:

Chen, Yu (Chen, Yu.) | Lu, Minyi (Lu, Minyi.) | Yang, Huazheng (Yang, Huazheng.) | Yao, Yingbang (Yao, Yingbang.) | Tao, Tao (Tao, Tao.) | Lu, Shengguo (Lu, Shengguo.) | Wang, Chao (Wang, Chao.) | Ramesh, Rajendran (Ramesh, Rajendran.) | Kendall, Michaela (Kendall, Michaela.) | Kendall, Kevin (Kendall, Kevin.) | Ouyang, Xiaoping (Ouyang, Xiaoping.) | Liang, Bo (Liang, Bo.)

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Abstract:

High power density and simple design are vital for these fuel cell-based portable power generation devices. This study provides an 8.6 g tubular SOFC with embedded a catalytic partial oxidation reformer, which is fabricated and operated for more than 100 h using propane/air. Nickel-iron nanosheets, as catalysts for reforming, supported on α-Al2O3 foam ceramic are synthesized by hydrothermal treatment. Testing for 80 h gives a power degradation of about 20% compared with the initial value. It is mainly attributed to sulfur-poisoning of nickel near anode/electrolyte interface according to transmission electron microscope (TEM) analysis. From TEM/energy dispersive spectroscopy line-scan results across the anode/electrolyte interface, sulfur as either aggregate at the nickel/yttria-stabilized zirconia grain boundaries or on the nickel grain surface, and no obvious carbon phase is founded. The maximum power density is 0.67 W cm−2 at 700 °C using propane/air (12 vol% propane), about 5% higher than the same cell using 20 vol% hydrogen. © 2020 Elsevier Ltd

Keyword:

Alumina Aluminum oxide Anodes Catalytic oxidation Catalytic reforming Grain boundaries Nanocatalysts Nickel Propane Solid oxide fuel cells (SOFC) Sulfur Transmission electron microscopy Zirconia

Author Community:

  • [ 1 ] [Chen, Yu]Guangdong Provincial Key Laboratory of Functional Soft Condensed Matter, School of Materials and Energy, Guangdong University of Technology, Guangzhou; 510006, China
  • [ 2 ] [Chen, Yu]Dongguan South China Design Innovation Institute, China
  • [ 3 ] [Lu, Minyi]Guangdong Provincial Key Laboratory of Functional Soft Condensed Matter, School of Materials and Energy, Guangdong University of Technology, Guangzhou; 510006, China
  • [ 4 ] [Yang, Huazheng]Guangdong Provincial Key Laboratory of Functional Soft Condensed Matter, School of Materials and Energy, Guangdong University of Technology, Guangzhou; 510006, China
  • [ 5 ] [Yang, Huazheng]ISOFC Dynamic Co., Ltd., Foshan, China
  • [ 6 ] [Yao, Yingbang]Guangdong Provincial Key Laboratory of Functional Soft Condensed Matter, School of Materials and Energy, Guangdong University of Technology, Guangzhou; 510006, China
  • [ 7 ] [Tao, Tao]Guangdong Provincial Key Laboratory of Functional Soft Condensed Matter, School of Materials and Energy, Guangdong University of Technology, Guangzhou; 510006, China
  • [ 8 ] [Lu, Shengguo]Guangdong Provincial Key Laboratory of Functional Soft Condensed Matter, School of Materials and Energy, Guangdong University of Technology, Guangzhou; 510006, China
  • [ 9 ] [Wang, Chao]Guangdong Provincial Key Laboratory of Functional Soft Condensed Matter, School of Materials and Energy, Guangdong University of Technology, Guangzhou; 510006, China
  • [ 10 ] [Ramesh, Rajendran]Department of Physics, Periyar University, Tamil Nadu; 636011, India
  • [ 11 ] [Kendall, Michaela]Adelan Ltd, Weekin Works, Harborne, United Kingdom
  • [ 12 ] [Kendall, Kevin]Adelan Ltd, Weekin Works, Harborne, United Kingdom
  • [ 13 ] [Ouyang, Xiaoping]School of Nuclear Science and Technology, Xi'an Jiaotong University, No. 28, Xianning West Road, Xi'an; 710049, China
  • [ 14 ] [Liang, Bo]Guangdong Provincial Key Laboratory of Functional Soft Condensed Matter, School of Materials and Energy, Guangdong University of Technology, Guangzhou; 510006, China
  • [ 15 ] [Liang, Bo]Dongguan South China Design Innovation Institute, China
  • [ 16 ] [Liang, Bo]ISOFC Dynamic Co., Ltd., Foshan, China

Reprint Author's Address:

  • [Ouyang, Xiaoping]School of Nuclear Science and Technology, Xi'an Jiaotong University, No. 28, Xianning West Road, Xi'an; 710049, China;;

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Source :

Applied Energy

ISSN: 0306-2619

Year: 2020

Volume: 272

9 . 7 4 6

JCR@2020

9 . 7 4 6

JCR@2020

ESI Discipline: ENGINEERING;

ESI HC Threshold:59

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 7

SCOPUS Cited Count: 19

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 9

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