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Abstract:
High power density and simple design are vital for these fuel cell-based portable power generation devices. This study provides an 8.6 g tubular SOFC with embedded a catalytic partial oxidation reformer, which is fabricated and operated for more than 100 h using propane/air. Nickel-iron nanosheets, as catalysts for reforming, supported on α-Al2O3 foam ceramic are synthesized by hydrothermal treatment. Testing for 80 h gives a power degradation of about 20% compared with the initial value. It is mainly attributed to sulfur-poisoning of nickel near anode/electrolyte interface according to transmission electron microscope (TEM) analysis. From TEM/energy dispersive spectroscopy line-scan results across the anode/electrolyte interface, sulfur as either aggregate at the nickel/yttria-stabilized zirconia grain boundaries or on the nickel grain surface, and no obvious carbon phase is founded. The maximum power density is 0.67 W cm−2 at 700 °C using propane/air (12 vol% propane), about 5% higher than the same cell using 20 vol% hydrogen. © 2020 Elsevier Ltd
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Applied Energy
ISSN: 0306-2619
Year: 2020
Volume: 272
9 . 7 4 6
JCR@2020
9 . 7 4 6
JCR@2020
ESI Discipline: ENGINEERING;
ESI HC Threshold:59
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 7
SCOPUS Cited Count: 19
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 9