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Abstract:
We demonstrate excellent superelasticity and giant elastocaloric effect in a directionally solidified Co50.7V333Ga16 alloy. Owing to the formation of [001](A) preferentially oriented columnar grains, the as-grown alloy displays nearly perfect superelastic behaviors with fully reversible compressive strain of up to 5.4%, narrow stress hysteresis of about 40 MPa and a wide operating temperature window from 258 to 373 K. Simultaneously, a giant adiabatic temperature change Delta T-ad ad of -18.7 K is obtained on removing a uniaxial stress of 400 MPa at room temperature, which is in good agreement with the theoretical values based on Maxwell relation (-19.0 K) and calorimetric measurements (-19.9 K). A large vertical bar Delta T-ad vertical bar of greater than 12.5 K is obtained over a wide temperature span of at least 115 K. Moreover, both superelasticity and elastocaloric effect remain good functional stability without any evident degradation for 100 cycles. (C) 2021 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
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SCRIPTA MATERIALIA
ISSN: 1359-6462
Year: 2021
Volume: 204
5 . 6 1 1
JCR@2020
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:36
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 2
SCOPUS Cited Count: 19
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 10