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Author:

Zhou, Xianglong (Zhou, Xianglong.) | Liu, Yao (Liu, Yao.) | Song, Xin (Song, Xin.) | Jia, Wentao (Jia, Wentao.) | Xiao, Andong (Xiao, Andong.) | Yuan, Tao (Yuan, Tao.) | Liu, Feng (Liu, Feng.) | Wang, Fang (Wang, Fang.) | Ma, Tianyu (Ma, Tianyu.)

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Abstract:

Precipitation of Sm/Cu-enriched cell boundary phase during isothermal aging plays a crucial role on the hard magnetic properties of the cellular nanostructured 2:17-type Sm-Co-Fe-Cu-Zr permanent magnets. However, this method offers only limited magnetic hardening effect in Fe-rich magnets as conventional thermal aging usually leads to decreased density of cell boundary precipitates. Here we report a stress-aging approach to rectify this limitation. As exhibited by a model magnet Sm25Co44.9Fe21.5Cu5.6Zr3.0 (wt.%), aging under 50 MPa uniaxial compressive stress for the same time at the same temperature can simultaneously enhance the intrinsic coercivity from 17.51 to 25.68 kOe and maximum energy product from 28.39 to 31.39 MGOe when compared with conventional isothermal aging. Detailed microstructural and microchemical investigations revealed that the magnetic performance enhancement stems from the retained [001] texture, the increased number density of Cu-enriched cell boundary precipitates, and the reduced stacking faults density at cell edges, which can significantly strengthen the magnetic domain wall pinning. Such microstructural improvements are contributed from the increased density of defects that promote the precipitate nucleation at early stage and the stress-induced dislocation re-arrangements that accelerate defects dissociation and atomic diffusion at the following stage, i.e. optimizing the thermodynamic-kinetic compromise of precipitation. Further study revealed that aging under higher stress leads to abnormal cell growth and weakened [001] texture due to the dynamic recrystallization effect, deteriorating the magnetic properties. Consequently, stress-aging provides a fresh freedom to manipulate the microstructure of Sm-Co-Fe-Cu-Zr magnets, but the stress magnitude should be carefully controlled to improve the magnetic performance. © 2021 Acta Materialia Inc.

Keyword:

Binary alloys Cell proliferation Copper alloys Defects Domain walls Iron alloys Isotherms Magnetic domains Textures Thermal aging Thermal cycling Zircaloy

Author Community:

  • [ 1 ] [Zhou, Xianglong]Frontier Institute of Science and Technology, State Key Laboratory for Mechanical Behavior of Materials, MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, Xi'an Jiaotong University, No.99 Yanxiang Road, Xi'an; 710049, China
  • [ 2 ] [Liu, Yao]Frontier Institute of Science and Technology, State Key Laboratory for Mechanical Behavior of Materials, MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, Xi'an Jiaotong University, No.99 Yanxiang Road, Xi'an; 710049, China
  • [ 3 ] [Song, Xin]Frontier Institute of Science and Technology, State Key Laboratory for Mechanical Behavior of Materials, MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, Xi'an Jiaotong University, No.99 Yanxiang Road, Xi'an; 710049, China
  • [ 4 ] [Jia, Wentao]Frontier Institute of Science and Technology, State Key Laboratory for Mechanical Behavior of Materials, MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, Xi'an Jiaotong University, No.99 Yanxiang Road, Xi'an; 710049, China
  • [ 5 ] [Xiao, Andong]Frontier Institute of Science and Technology, State Key Laboratory for Mechanical Behavior of Materials, MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, Xi'an Jiaotong University, No.99 Yanxiang Road, Xi'an; 710049, China
  • [ 6 ] [Yuan, Tao]Frontier Institute of Science and Technology, State Key Laboratory for Mechanical Behavior of Materials, MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, Xi'an Jiaotong University, No.99 Yanxiang Road, Xi'an; 710049, China
  • [ 7 ] [Yuan, Tao]The Southwest Applied Magnetism Research Institute, Mianyang; 621000, China
  • [ 8 ] [Liu, Feng]State Key Laboratory of Solidification Processing and Analytical & Testing Center, Northwestern Polytechnical University, Xi'an; 710072, China
  • [ 9 ] [Wang, Fang]Key Laboratory of Magnetic Molecules and Magnetic Information Materials, Ministry of Education, Linfen; 041004, China
  • [ 10 ] [Ma, Tianyu]Frontier Institute of Science and Technology, State Key Laboratory for Mechanical Behavior of Materials, MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, Xi'an Jiaotong University, No.99 Yanxiang Road, Xi'an; 710049, China

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Source :

Materialia

Year: 2021

Volume: 20

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 13

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 10

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