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Author:

Wang, Qiming (Wang, Qiming.) | Wang, Zhenzhen (Wang, Zhenzhen.) | Kamimoto, Takahiro (Kamimoto, Takahiro.) | Deguchi, Yoshihiro (Deguchi, Yoshihiro.) | Cao, Shengli (Cao, Shengli.) | Wen, Du (Wen, Du.) | Takahara, Daichi (Takahara, Daichi.)

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Abstract:

Tunable diode laser absorption spectroscopy (TDLAS) is a widely used diagnostic technique due to its high sensitivity, fast response, low cost, and other merits. Hydrocarbon detection is a field of great interest in the application of tunable diode lasers as hydrocarbons are fundamental molecules in many industrial processes. Many tunable diode lasers are only suitable for single species detection due to the short scanning range and in real situations. However, different hydrocarbon species tend to exist simultaneously. Here we present a laser system based on the difference-frequency generation (DFG) method for simultaneous hydrocarbon mixtures detection. The direct absorption spectra of different hydrocarbons covering various groups (e.g., alkane, olefin, and aromatic) were measured. The measurements of the concentration dependence of absorbance for each molecule were carried out. The R2 values were larger than 0.997, which demonstrated the system can measure hydrocarbons covering different molecular classes accurately. The mixture components were identified using the independent component analysis and quantitative analysis was performed using the classical least-squares method. Future studies will focus on the validation of the system in actual processes. © 2021 Elsevier B.V.

Keyword:

Absorption spectroscopy Aromatic hydrocarbons Diodes Independent component analysis Least squares approximations Mixtures Molecules Semiconductor lasers

Author Community:

  • [ 1 ] [Wang, Qiming]Graduate School of Advanced Technology and Science, Tokushima University, Tokushima; 770-8501, Japan
  • [ 2 ] [Wang, Zhenzhen]Graduate School of Advanced Technology and Science, Tokushima University, Tokushima; 770-8501, Japan
  • [ 3 ] [Wang, Zhenzhen]State Key Laboratory of Multiphase Flow in Power Engineering, Xi'an Jiaotong University, Xi'an; 710049, China
  • [ 4 ] [Kamimoto, Takahiro]Graduate School of Advanced Technology and Science, Tokushima University, Tokushima; 770-8501, Japan
  • [ 5 ] [Deguchi, Yoshihiro]Graduate School of Advanced Technology and Science, Tokushima University, Tokushima; 770-8501, Japan
  • [ 6 ] [Deguchi, Yoshihiro]State Key Laboratory of Multiphase Flow in Power Engineering, Xi'an Jiaotong University, Xi'an; 710049, China
  • [ 7 ] [Cao, Shengli]Graduate School of Advanced Technology and Science, Tokushima University, Tokushima; 770-8501, Japan
  • [ 8 ] [Cao, Shengli]School of Power and Energy Engineering, Xi'an Jiaotong University, Xi'an; 710049, China
  • [ 9 ] [Wen, Du]Graduate School of Advanced Technology and Science, Tokushima University, Tokushima; 770-8501, Japan
  • [ 10 ] [Wen, Du]State Key Laboratory of Multiphase Flow in Power Engineering, Xi'an Jiaotong University, Xi'an; 710049, China
  • [ 11 ] [Takahara, Daichi]Graduate School of Advanced Technology and Science, Tokushima University, Tokushima; 770-8501, Japan

Reprint Author's Address:

  • Y. Deguchi;;Graduate School of Advanced Technology and Science, Tokushima University, Tokushima, 2-1, Minamijyosanjima, 770-8506, Japan;;email: ydeguchi@tokushima-u.ac.jp;;

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Source :

Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

ISSN: 1386-1425

Year: 2021

Volume: 265

4 . 0 9 8

JCR@2020

ESI Discipline: CHEMISTRY;

ESI HC Threshold:32

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 8

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 8

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