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Author:

Wang, Yiran (Wang, Yiran.) | Lan, Tian (Lan, Tian.) | Ali, Raza (Ali, Raza.) | Xu, Jimin (Xu, Jimin.) | Liu, Xiangyang (Liu, Xiangyang.) | He, Maogang (He, Maogang.)

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SCIE EI Scopus Web of Science

Abstract:

Isopropanol and isobutanol are potentially partial substitutes for gasoline. The critical properties of isoalcohol-gasoline blends are of great importance to optimize their combustion and emission performance in engines. In this paper, the critical temperature (T-c) and critical pressure (p(c)) of eight miscible systems (isopropanol/isobutanol + n-hexane, isopropanol/isobutanol + n-heptane, isopropanol/isobutanol + n-octane, isopropanol/isobutanol + n-heptane + isooctane) were measured by the flow method in the range of 497.69-569.21 K and 2.495-4.766 MPa. Experimental results show that the addition of isopropanol and isobutanol can significantly reduce the T-c of C-6-C-8 alkanes by 0-60.85 K and increase the pc by 0-2.271 MPa. A model for calculating the T-c and p(c) of these mixtures is presented based on the Redlich-Kister equations. The maximum average absolute relative deviations of the T-c and p(c) are 0.08% and 0.46%, respectively.

Keyword:

Critical pressure Critical temperature Flow method Isoalcohol

Author Community:

  • [ 1 ] [Wang, Yiran]Xi An Jiao Tong Univ, Sch Energy & Power Engn, Key Lab Thermal Fluid Sci & Engn MOE, Xian 710049, Peoples R China
  • [ 2 ] [Lan, Tian]Xi An Jiao Tong Univ, Sch Energy & Power Engn, Key Lab Thermal Fluid Sci & Engn MOE, Xian 710049, Peoples R China
  • [ 3 ] [Ali, Raza]Xi An Jiao Tong Univ, Sch Energy & Power Engn, Key Lab Thermal Fluid Sci & Engn MOE, Xian 710049, Peoples R China
  • [ 4 ] [Xu, Jimin]Xi An Jiao Tong Univ, Sch Energy & Power Engn, Key Lab Thermal Fluid Sci & Engn MOE, Xian 710049, Peoples R China
  • [ 5 ] [Liu, Xiangyang]Xi An Jiao Tong Univ, Sch Energy & Power Engn, Key Lab Thermal Fluid Sci & Engn MOE, Xian 710049, Peoples R China
  • [ 6 ] [He, Maogang]Xi An Jiao Tong Univ, Sch Energy & Power Engn, Key Lab Thermal Fluid Sci & Engn MOE, Xian 710049, Peoples R China

Reprint Author's Address:

  • X. Liu;;Key Laboratory of Thermal Fluid Science and Engineering of MOE, School of Energy and Power Engineering, Xi'an Jiaotong University, Xi'an, 710049, China;;email: lxyyang@mail.xjtu.edu.cn;;

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Source :

JOURNAL OF SUPERCRITICAL FLUIDS

ISSN: 0896-8446

Year: 2022

Volume: 182

4 . 5 7 7

JCR@2020

ESI Discipline: CHEMISTRY;

ESI HC Threshold:6

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 7

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