A　comprehensive　experimental　and　kinetic　study　on　the　low　temperature　oxidation　and　pyrolysis　of　iso-octane　and　CNPC　92#　was　conducted.　Species　profiles　measurements　were　performed　in　a　jet-stirred　reactor　(JSR)　at　the　temperature　range　of　500–1300　K　under　atmospheric　pressure,　with　a　fixed　residence　time　of　2.0　s　and　for　the　equivalence　ratios　ranging　from　0.5　to　∞　(pyrolysis).　Three　kinetic　models　were　adopted　to　simulate　mole　fraction　profiles　of　major　species　in　the　oxidation　and　pyrolysis　of　iso-octane,　and　sensitivity　analysis　was　also　conducted　using　the　model　which　preformed　best.　In　addition,　a　detailed　gasoline　surrogate　kinetic　model　was　developed　including　five　representative　fuels　in　gasoline.　This　kinetic　model　and　a　TRF　model　containing　three　individual　fuels　from　KAUST　were　verified　by　low　temperature　oxidation　and　pyrolysis　experiment　data　of　CNPC　92#.　The　results　show　that　prediction　profiles　by　the　five-component　model　and　measured　mole　fraction　of　major　intermediates　are　in　a　better　agreement　than　TRF　model.　©　2021　Elsevier　Ltd