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Author:

Chen, Hongyu (Chen, Hongyu.) | Song, Xin (Song, Xin.) | Zhou, Xianglong (Zhou, Xianglong.) | Jia, Wentao (Jia, Wentao.) | Yuan, Tao (Yuan, Tao.) | Ma, Tianyu (Ma, Tianyu.)

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Abstract:

Pinning-controlled Sm2(Co, M)17 (M = Fe, Cu, and Zr) magnets with cellular nanostructures are the strongest high-temperature permanent magnets. The squareness factor of such magnets is smaller than those of nucleation-controlled permanent magnets, leading to a lower-than-ideal maximum energy product. One of the main reasons for this poor squareness is that the pinning strength is weaker at cell edges than at 1:5H cell boundaries. However, the structure of these edges remains a topic of debate. To identify the microstructure of cell edges, electron diffraction, TEM bright/dark field imaging, and HRTEM imaging on a model magnet Sm25Co50.2Fe16.2Cu5.6Zr3.0 (mass fraction, %) were performed using both [100]2:17R and [101]2:17R zone axes. The results revealed a rhombohedral 2:17R' phase at some of the edges, with one faulting basal layer in the 2:17R lattice. Further comparative investigations revealed that all the extra superlattice reflections result from the 2:17R' phase, excluding the previously identified 2:17H or Smn + 1Co5n - 1 or their mixture that can only produce a part of such superlattice reflections. Owing to the 2:17R' phase with a faulted basal plane, the free energy at the cell edges is higher than that of the 2:17R cell interiors, leading to repulsive domain-wall-pinning unfavorable for the squareness factor. This study provides important evidence for understanding the microstructural origin of the poor squareness factor obtained for Sm2(Co, M)17 permanent magnets. © 2021, Science Press. All right reserved.

Keyword:

Binary alloys Cells Cobalt alloys Copper alloys Cytology Electron diffraction Free energy Iron alloys Permanent magnets Samarium alloys Zircaloy

Author Community:

  • [ 1 ] [Chen, Hongyu]Frontier Institute of Science and Technology and State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an; 710049, China
  • [ 2 ] [Song, Xin]Frontier Institute of Science and Technology and State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an; 710049, China
  • [ 3 ] [Zhou, Xianglong]Frontier Institute of Science and Technology and State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an; 710049, China
  • [ 4 ] [Jia, Wentao]Frontier Institute of Science and Technology and State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an; 710049, China
  • [ 5 ] [Yuan, Tao]Frontier Institute of Science and Technology and State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an; 710049, China
  • [ 6 ] [Yuan, Tao]The Southwest Applied Magnetism Research Institute, Mianyang; 621000, China
  • [ 7 ] [Ma, Tianyu]Frontier Institute of Science and Technology and State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an; 710049, China

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Source :

Acta Metallurgica Sinica

ISSN: 0412-1961

Year: 2021

Issue: 12

Volume: 57

Page: 1637-1644

1 . 2 5 1

JCR@2020

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:36

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 3

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 14

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