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Author:

Liang, Jie (Liang, Jie.) | Zhao, Xuetong (Zhao, Xuetong.) | Kang, Shenglin (Kang, Shenglin.) | Guo, Jing (Guo, Jing.) | Chen, Zhiling (Chen, Zhiling.) | Long, Yuli (Long, Yuli.) | Zeng, Qian (Zeng, Qian.) | Sun, Jianjie (Sun, Jianjie.) | Yang, Lijun (Yang, Lijun.) | Liao, Ruijin (Liao, Ruijin.) | Randall, Clive A (Randall, Clive A.)

Indexed by:

EI SCIE Scopus Engineering Village

Abstract:

In this work, we demonstrate a hybrid cold sintering/spark plasma sintering (CSP-SPS) process to densify ZnO ceramic with controlled grain growth. The densification of ZnO is initially activated at 85 °C, and high densities (>98%) are achieved at 200–300 °C in only 5 min with a low assisted pressure of 3.8–50 MPa. The microstructure of ZnO grains experiences a mild coarsening from ~205–680 nm during the CSP-SPS. In comparison, a much higher temperature (>770 °C) is required to sinter ZnO ceramic via SPS, and the grain size exhibits an obvious overgrowth to ~10 µm. The calculated apparent activation energy of grain growth using CSP-SPS is 69.3 ± 6 kJ/mol, which is much lower than that of SPS samples with 296.8 ± 59 kJ/mol. In addition, the conduction mechanism of the CSP-SPS and SPS samples is investigated using impedance spectroscopy. Overall, CSP-SPS is promising for the fabrication of fine ceramics with mild sintering conditions. © 2022 Elsevier Ltd

Keyword:

Activation energy Coarsening Grain growth II-VI semiconductors Microstructural evolution Ostwald ripening Spark plasma sintering Zinc oxide

Author Community:

  • [ 1 ] [Liang, Jie]State Key Laboratory of Power Transmission Equipment & System Security and New Technology, Chongqing University, Chongqing; 400044, China
  • [ 2 ] [Zhao, Xuetong]State Key Laboratory of Power Transmission Equipment & System Security and New Technology, Chongqing University, Chongqing; 400044, China
  • [ 3 ] [Kang, Shenglin]State Key Laboratory of Power Transmission Equipment & System Security and New Technology, Chongqing University, Chongqing; 400044, China
  • [ 4 ] [Guo, Jing]State Key Laboratory for Mechanical Behaviour of Materials & School of Materials Science and Engineering, Xi'an Jiaotong University, Xi'an, 710049, China
  • [ 5 ] [Chen, Zhiling]State Key Laboratory of Power Transmission Equipment & System Security and New Technology, Chongqing University, Chongqing; 400044, China
  • [ 6 ] [Long, Yuli]State Key Laboratory of Power Transmission Equipment & System Security and New Technology, Chongqing University, Chongqing; 400044, China
  • [ 7 ] [Zeng, Qian]State Key Laboratory of Power Transmission Equipment & System Security and New Technology, Chongqing University, Chongqing; 400044, China
  • [ 8 ] [Sun, Jianjie]State Key Laboratory of Power Transmission Equipment & System Security and New Technology, Chongqing University, Chongqing; 400044, China
  • [ 9 ] [Yang, Lijun]State Key Laboratory of Power Transmission Equipment & System Security and New Technology, Chongqing University, Chongqing; 400044, China
  • [ 10 ] [Liao, Ruijin]State Key Laboratory of Power Transmission Equipment & System Security and New Technology, Chongqing University, Chongqing; 400044, China
  • [ 11 ] [Randall, Clive A.]Materials Research Institute and Department of Materials Science & Engineering, The Pennsylvania State University, University Park; PA; 16802, United States
  • [ 12 ] [Liang, Jie]Chongqing Univ, State Key Lab Power Transmiss Equipment & Syst Sec, Chongqing 400044, Peoples R China
  • [ 13 ] [Zhao, Xuetong]Chongqing Univ, State Key Lab Power Transmiss Equipment & Syst Sec, Chongqing 400044, Peoples R China
  • [ 14 ] [Kang, Shenglin]Chongqing Univ, State Key Lab Power Transmiss Equipment & Syst Sec, Chongqing 400044, Peoples R China
  • [ 15 ] [Chen, Zhiling]Chongqing Univ, State Key Lab Power Transmiss Equipment & Syst Sec, Chongqing 400044, Peoples R China
  • [ 16 ] [Long, Yuli]Chongqing Univ, State Key Lab Power Transmiss Equipment & Syst Sec, Chongqing 400044, Peoples R China
  • [ 17 ] [Zeng, Qian]Chongqing Univ, State Key Lab Power Transmiss Equipment & Syst Sec, Chongqing 400044, Peoples R China
  • [ 18 ] [Sun, Jianjie]Chongqing Univ, State Key Lab Power Transmiss Equipment & Syst Sec, Chongqing 400044, Peoples R China
  • [ 19 ] [Yang, Lijun]Chongqing Univ, State Key Lab Power Transmiss Equipment & Syst Sec, Chongqing 400044, Peoples R China
  • [ 20 ] [Liao, Ruijin]Chongqing Univ, State Key Lab Power Transmiss Equipment & Syst Sec, Chongqing 400044, Peoples R China
  • [ 21 ] [Guo, Jing]Xi An Jiao Tong Univ, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China
  • [ 22 ] [Guo, Jing]Xi An Jiao Tong Univ, Sch Mat Sci & Engn, Xian 710049, Peoples R China
  • [ 23 ] [Randall, Clive A.]Penn State Univ, Mat Res Inst, University Pk, PA 16802 USA
  • [ 24 ] [Randall, Clive A.]Penn State Univ, Dept Mat Sci & Engn, University Pk, PA 16802 USA

Reprint Author's Address:

  • [Zhao, X.]State Key Laboratory of Power Transmission Equipment & System Security and New Technology, China;;

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Source :

Journal of the European Ceramic Society

ISSN: 0955-2219

Year: 2022

Issue: 13

Volume: 42

Page: 5738-5746

5 . 3 0 2

JCR@2020

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:7

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 19

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 17

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