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Author:

Jerzak, Wojciech (Jerzak, Wojciech.) | Gao, Ningbo (Gao, Ningbo.) | Kalemba-Rec, Izabela (Kalemba-Rec, Izabela.) | Magdziarz, Aneta (Magdziarz, Aneta.)

Indexed by:

SCIE EI Scopus Web of Science

Abstract:

This study describes an experimental investigation comparing the effects of two catalysts (ZSM-5 and Zeolite Y) on intermediate pyrolysis. The catalysts are characterized by different acidities, expressed by silica-to-alumina ratios of 352 (ZSM-5) and 26 (Zeolite Y). The post-extraction rapeseed meal was pyrolysed in a fixed-bed furnace at a temperature of 500 degrees C, and the pyrolysis products (char, liquid phase, and pyro-gas) were char-acterized in detail. The catalysts were assessed based on their reusage capability. Five-fold more carbon was deposited on Zeolite Y than on ZSM-5 after 10-fold use during the pyrolysis of rapeseed meal. Moreover, the ultimate analysis of the catalysts showed increases in the hydrogen and nitrogen contents, which were signifi-cantly higher for Zeolite Y than those for ZSM-5. The catalysts showed different effects on the properties of the products. Better-quality pyro-gas was obtained with Zeolite Y, but reusage of this catalyst resulted in decreases in the hydrogen and carbon oxide concentrations. Compared to Zeolite Y, ZSM-5 afforded bio-oil with a lower oxygen content. Phenols and ketones were dominant compounds in both bio-oils. Regeneration of Zeolite Y caused to increase of specific surface area.

Keyword:

bio-oil catalytic pyrolysis char coke Zeolite Y ZSM-5

Author Community:

  • [ 1 ] [Jerzak, Wojciech]AGH Univ Sci & Technol, 30 Mickiewicza Ave, PL-30059 Krakow, Poland
  • [ 2 ] [Kalemba-Rec, Izabela]AGH Univ Sci & Technol, 30 Mickiewicza Ave, PL-30059 Krakow, Poland
  • [ 3 ] [Magdziarz, Aneta]AGH Univ Sci & Technol, 30 Mickiewicza Ave, PL-30059 Krakow, Poland
  • [ 4 ] [Gao, Ningbo]Xi An Jiao Tong Univ, Sch Energy & Power Engn, Xian 710049, Peoples R China

Reprint Author's Address:

  • [Jerzak, W.]AGH University of Science and Technology, 30 Mickiewicza Av., Poland;;

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Source :

CATALYSIS TODAY

ISSN: 0920-5861

Year: 2022

Volume: 404

Page: 63-77

6 . 7 6 6

JCR@2020

ESI Discipline: CHEMISTRY;

ESI HC Threshold:6

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 17

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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