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Abstract:
(1-x)Ba0.65Bi0.07Sr0.245TiO3-xR2O3 (BBST-xR) ceramics embellished by lanthanides (La, Yb, Gd) were synthesized in this study, and the effects in properties were ascertained. The results show that lanthanides with smaller ionic radius differences and larger relative mass will effectively limit mass transport of other cations and restrain grain growth. It is also found that the paraelectric phase of ceramics can be stabilized by decreasing the ionic radius of lanthanides. In particular, the addition of La unfolds the exceptional recoverable storage density (Wrec) up to 2.23 J/cm3 and efficiency (η) of ∼76.7% under 280 kV/cm. Finite element simulation and PFM observation also further explain the reasons for the excellent performance. Concurrently, BBST-0.015La ceramic exhibits outstanding thermostability from 30 °C to 150 °C and frequency stabilization from 1 Hz to 300 Hz which indicates the potentiality of application in actual surroundings. © 2022 Elsevier Ltd and Techna Group S.r.l.
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Ceramics International
ISSN: 0272-8842
Year: 2023
Issue: 2
Volume: 49
Page: 2626-2637
4 . 5 2 7
JCR@2020
ESI Discipline: MATERIALS SCIENCE;
Cited Count:
SCOPUS Cited Count: 8
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 10