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Author:

Yu Yaping (Yu Yaping.) | Wu Yang (Wu Yang.) | Zhang Andong (Zhang Andong.) | Li Cheng (Li Cheng.) | Tang Zheng (Tang Zheng.) | Ma Wei (Ma Wei.) | Wu Yonggang (Wu Yonggang.) | Li Weiwei (Li Weiwei.)

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Abstract:

Conjugated polymers consisting of diketopyrrolopyrrole (DPP) units have been successfully applied in field-effect transistors (FETs) and polymer solar cells (PSCs), while most of the DPP polymers were designed as symmetric structures containing identical aromatic linkers. In this manuscript, we design a new asymmetric DPP polymer with varied aromatic linkers in the backbone for application in FETs and PSCs. The designation provides the chance to finely adjust the energy levels of conjugated polymers so as to influence the device performance. The asymmetric polymer exhibits highly crystalline properties, high hole mobilities of 3.05 cm<sup>2</sup> V<sup>-1</sup> s<sup>-1</sup> in FETs, and a high efficiency of 5.9% in PSCs with spectra response from 300 to 850 nm. Morphology investigation demonstrates that the asymmetric polymer has a large crystal domain in blended thin films, indicating that the solar cell performance can be further enhanced by optimizing the microphase separation. The study reveals that the asymmetric design via adjusting the aromatic linkers in DPP polymers is a useful route toward flexible electronic devices.

Keyword:

asymmetric polymer conjugated polymer crystalline diketopyrrolopyrrole field-effect transistors polymer solar cells

Author Community:

  • [ 1 ] [Yu Yaping;Wu Yonggang]College of Chemistry and Environmental Science, Hebei University , Baoding 071002, China.
  • [ 2 ] [Yu Yaping;Zhang Andong;Li Cheng;Li Weiwei]Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences , Beijing 10090, China.
  • [ 3 ] [Wu Yang;Ma Wei]State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University , Xi'an 710049, People's Republic of China.
  • [ 4 ] [Tang Zheng]Institut für Angewandte Photophysik, Technische Universität Dresden , George-Bähr-Strasse 1, 01069 Dresden, Germany.

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Source :

ACS applied materials & interfaces

ISSN: 1944-8252

Year: 2016

Issue: 44

Volume: 8

Page: 30328-30335

7 . 5 0 4

JCR@2016

9 . 2 2 9

JCR@2020

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:239

JCR Journal Grade:2

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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