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With a batch type photocatalytic reactor, the kinetics of the photocatalytic degradation of acetaldehyde is investigated using gas chromatography. It is found that the reaction is in photon transfer controlled step with high initial concentration of acetaldehyde and low light intensity of ultraviolet on the surface of catalyst, and the reaction rate is proportional to light intensity. If the light intensity is high, the degradation of acetaldehyde can be described by Langmuir-Hinshelwood equation. When the initial concentration of acetaldehyde in the reactor is low, the degradation is a typical first-order reaction regardless of light intensity. With the increase of the light intensity, the reaction rate constantly rises. As the light intensity exceeds 11.6 W/m2, the reaction becomes surface controlled, and further increase of light intensity has no effect on the reaction rate.
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Hsi-An Chiao Tung Ta Hsueh/Journal of Xi'an Jiaotong University
ISSN: 0253-987X
Year: 2006
Issue: 7
Volume: 40
Page: 856-859
Cited Count:
WoS CC Cited Count: 1
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 5
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