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Abstract:
Recently electrostrictive effect in ferroelectrics has attracted much attention, since the electric field-induced strain based on such an effect possesses an ultra-low hysteresis, which is of special interest to both fundamental research and potential application in high-precision actuators. In this paper, we propose a strategy to obtain high electrostrictive properties in ABO3 perovskite structure BaTiO3 (BT)-based ferroelectric ceramics by means of doping. The doping element, amount, valence as well as position are specified according to this strategy. It is suggested that B-site Sn4+-doped BT, i.e., Ba(Ti1-xSnx)O3 (BTS), would possess superior electrostrictive properties. The structural evolution and electrical properties of BTS ferroelectric ceramics were investigated in detail in order to verify this deduction. Besides the ferroelectric-to-relaxor transition with respect to the increase of x from 0.06 to 0.11, expected and high electric field-induced strain (> 0.08% at 40 kV/cm) with a very ultra-low hysteresis (< 8%) is obtained in x = 0.10–0.11 compositions. High longitudinal electrostrictive coefficient Q33 ranges from to 0.0398 m4/C2 to 0.0515 m4/C2 accompanying with temperature- and composition-insensitive characteristics. These results not only prove the effectiveness of this strategy, but also pave a way to search for novel kinds of electrostrictive systems in ferroelectrics. © 2018 Elsevier Ltd and Techna Group S.r.l.
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Ceramics International
ISSN: 0272-8842
Year: 2018
Issue: 17
Volume: 44
Page: 21816-21824
3 . 4 5
JCR@2018
4 . 5 2 7
JCR@2020
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:182
JCR Journal Grade:2
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 28
SCOPUS Cited Count: 47
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 9