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Abstract:
Two new Co(II) coordination polymer, namely [Co2(L) 2(H2O)]n (1) and [Co(L)(phen)(H 2O)]n·xH2O (2) (H2L = 5-(benzyloxy)isophthalic acid, phen = 1,10-phenanthroline) have been hydrothermally synthesized and characterized by elemental analysis, powder X-ray diffraction, thermal analysis and single crystal X-ray analysis. The molecular structure of 1 contains two Co(II) ions, two L2- ligands and one coordinated water molecule, which further extends into a complicated 3D framework with the tails of L2- ligands filling in the hexagonal channels, and the molecular structure of 2 contains one Co(II) ions, one L2- ligands, one phen ligands, one coordinated water molecule and half of the water molecule of crystallization, which further extends into a 1D chain structure. In addition, photocatalytic investigation on compounds 1 and 2 reveals that they are active catalyst for degradation of methyl blue.© 2013 Elsevier B.V. All rights reserved.
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Source :
Journal of Molecular Structure
ISSN: 0022-2860
Year: 2014
Issue: 1
Volume: 1059
Page: 294-298
1 . 6 0 2
JCR@2014
3 . 1 9 6
JCR@2020
ESI Discipline: CHEMISTRY;
ESI HC Threshold:221
JCR Journal Grade:3
CAS Journal Grade:4
Cited Count:
WoS CC Cited Count: 11
SCOPUS Cited Count: 14
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 3
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