The　multi-cations　doped　LiVPO4F,　nominally　Li0.97Cr0.01V0.95Al0.01Nb0.02PO4F0.97,　is　prepared　by　Chromium　(Cr)　doping　on　lithium　site　and　Al-Nb　co-doping　on　vanadium　site　via　a　conventional　carbothermal　reduction　(CTR)　route.　The　crystallographic　lattice　volume,　particle　size　and　morphology　are　not　obviously　changed　comparing　with　un-doped　LiVPO4F.　However,　the　high　rate　and　lifetime　cycling　performances　are　noticeably　improved　although　the　capacities　at　very　low　currents　are　slightly　decreased.　The　reversible　capacity　at　1/10　C,　1　C,　2　C　and　4　C　of　the　pristine　LiVPO4F　is　143　mA　h　g(-1),　99　mA　h　g(-1),　86　mA　h　g(-1)　and　70　mA　h　g(-1),　respectively,　while　that　of　the　doped　counterpart　is　138　mA　h　g(-1),　102　mA　h　g(-1),　95　mA　h　g(-1)　and　82　mA　h　g(-1),　respectively.　The　capacity　retention　after　100　galvanostatic　cycles　at　1.5　C　is　enhanced　from　85.4%　to　90.9%　by　such　multi-cations　doping.　Moreover,　the　initial　coulombic　efficiency　is　significantly　increased　from　81.8%　to　90.3%　as　well.