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Abstract:
A methacryl ethyl-functionalized soluble polypyrrole was designed and prepared by chemical oxidative polymerization for rapid fabrication of high-aspect-ratio pillar arrays. The chemical structures of the pyrrole derivative and the corresponding polypyrrole were characterized by FFIR and H-1 NMR The polypyrrole with a weight average molecular weight (M-w) of 7376 exhibits good solubility in several organic solvents, favorable thin film forming ability and two UV-Vis absorption peaks at 280 and 380 nm in tetrahydrofuran solution. The dilute chloroform solution of the polypyrrole is a Newtonian fluid with a low viscosity and shows a significant increase in the electrical conductivity with increasing the polypyrrole content. Moreover, an insulating photoresist can be transformed into a conductive photoresist by doping this polypyrrole. Electrowetting driven structure formation experiments have confirmed that the conductive photoresist can fulfill rapid fabrication of higher-aspect-ratio pillar arrays compared with the insulating photoresist. (C) 2016 Elsevier B.V. All rights reserved.
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REACTIVE & FUNCTIONAL POLYMERS
ISSN: 1381-5148
Year: 2017
Volume: 111
Page: 44-52
2 . 9 7 5
JCR@2017
3 . 9 7 5
JCR@2020
ESI Discipline: CHEMISTRY;
ESI HC Threshold:160
JCR Journal Grade:2
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 10
SCOPUS Cited Count: 11
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 3