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Author:

He, Kai (He, Kai.) | Yao, Zhenpeng (Yao, Zhenpeng.) | Hwang, Sooyeon (Hwang, Sooyeon.) | Li, Na (Li, Na.) | Sun, Ke (Sun, Ke.) | Gan, Hong (Gan, Hong.) | Du, Yaping (Du, Yaping.) | Zhang, Hua (Zhang, Hua.) | Wolyerton, Chris (Wolyerton, Chris.) | Su, Dong (Su, Dong.)

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SCIE PubMed EI Scopus

Abstract:

Two-dimensional (2D) transition metal chalcogenides have been widely studied and utilized as electrode materials for lithium ion batteries due to their unique layered structures to accommodate reversible lithium insertion. Real-time observation and mechanistic understanding of the phase transformations during lithiation of these materials are critically important for improving battery performance by controlling structures and reaction pathways. Here, we use in situ transmission electron microscopy methods to study the structural, morphological, and chemical evolutions in individual copper sulfide (CuS) nanoflakes during lithiation. We report a highly kinetically driven phase transformation in which lithium ions rapidly intercalate into the 2D van der Waals-stacked interlayers in the initial stage, and further lithiation induces the Cu extrusion via a displacement reaction mechanism that is different from the typical conversion reactions. Density functional theory calculations have confirmed both the thermodynamically favored and the kinetically driven reaction pathways. Our findings elucidate the reaction pathways of the Li/CuS system under nonequilibrium conditions and provide valuable insight into the atomistic lithiation mechanisms of transition metal sulfides in general.

Keyword:

Copper sulfides CuS electrochemistry kinetics in situ TEM lithium ion battery

Author Community:

  • [ 1 ] [He, Kai; Yao, Zhenpeng; Wolyerton, Chris] Northwestern Univ, Dept Mat Sci & Engn, Evanston, IL 60208 USA
  • [ 2 ] [He, Kai; Hwang, Sooyeon; Su, Dong] Brookhaven Natl Lab, Ctr Funct Nanomat, Upton, NY 11953 USA
  • [ 3 ] [Li, Na; Du, Yaping] Xi An Jiao Tong Univ, State Key Lab Mech Behav Mat, Frontier Inst Sci & Technol, Coll Sci, Xian 710054, Shaanxi, Peoples R China
  • [ 4 ] [Sun, Ke; Gan, Hong] Brookhaven Natl Lab, Energy Sci Directorate, Upton, NY 11953 USA
  • [ 5 ] [Zhang, Hua] Nanyang Technol Univ, Sch Mat Sci & Engn, Ctr Programmable Mat, Singapore 639798, Singapore
  • [ 6 ] [He, Kai]Northwestern Univ, Dept Mat Sci & Engn, Evanston, IL 60208 USA
  • [ 7 ] [Yao, Zhenpeng]Northwestern Univ, Dept Mat Sci & Engn, Evanston, IL 60208 USA
  • [ 8 ] [Wolyerton, Chris]Northwestern Univ, Dept Mat Sci & Engn, Evanston, IL 60208 USA
  • [ 9 ] [He, Kai]Brookhaven Natl Lab, Ctr Funct Nanomat, Upton, NY 11953 USA
  • [ 10 ] [Hwang, Sooyeon]Brookhaven Natl Lab, Ctr Funct Nanomat, Upton, NY 11953 USA
  • [ 11 ] [Su, Dong]Brookhaven Natl Lab, Ctr Funct Nanomat, Upton, NY 11953 USA
  • [ 12 ] [Li, Na]Xi An Jiao Tong Univ, State Key Lab Mech Behav Mat, Frontier Inst Sci & Technol, Coll Sci, Xian 710054, Shaanxi, Peoples R China
  • [ 13 ] [Du, Yaping]Xi An Jiao Tong Univ, State Key Lab Mech Behav Mat, Frontier Inst Sci & Technol, Coll Sci, Xian 710054, Shaanxi, Peoples R China
  • [ 14 ] [Sun, Ke]Brookhaven Natl Lab, Energy Sci Directorate, Upton, NY 11953 USA
  • [ 15 ] [Gan, Hong]Brookhaven Natl Lab, Energy Sci Directorate, Upton, NY 11953 USA
  • [ 16 ] [Zhang, Hua]Nanyang Technol Univ, Sch Mat Sci & Engn, Ctr Programmable Mat, Singapore 639798, Singapore

Reprint Author's Address:

  • Northwestern Univ, Dept Mat Sci & Engn, Evanston, IL 60208 USA.; He, K; Su, D (reprint author), Brookhaven Natl Lab, Ctr Funct Nanomat, Upton, NY 11953 USA.

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Source :

NANO LETTERS

ISSN: 1530-6984

Year: 2017

Issue: 9

Volume: 17

Page: 5726-5733

1 2 . 0 8

JCR@2017

1 1 . 1 8 9

JCR@2020

ESI Discipline: PHYSICS;

ESI HC Threshold:120

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 48

SCOPUS Cited Count: 58

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 7

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