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Author:

Jin Li (Jin Li.) | Huo Renjie (Huo Renjie.) | Guo Runping (Guo Runping.) | Li Fei (Li Fei.) | Wang Dawei (Wang Dawei.) | Tian Ye (Tian Ye.) | Hu Qingyuan (Hu Qingyuan.) | Wei Xiaoyong (Wei Xiaoyong.) | He Zhanbing (He Zhanbing.) | Yan Yan (Yan Yan.) | Liu Gang (Liu Gang.)

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Abstract:

The electrostrictive effect has some advantages over the piezoelectric effect, including temperature stability and hysteresis-free character. In the present work, we report the diffuse phase transitions and electrostrictive properties in lead-free Fe<sup>3+</sup>-doped 0.5Ba(Zr<sub>0.2</sub>Ti<sub>0.8</sub>)O<sub>3</sub>-0.5(Ba<sub>0.7</sub>Ca<sub>0.3</sub>)TiO<sub>3</sub> (BZT-0.5BCT) ferroelectric ceramics. The doping concentration was set from 0.25 to 2 mol %. It is found that by introducing Fe<sup>3+</sup> ion into BZT-0.5BCT, the temperature corresponding to permittivity maximum T<sub>m</sub> was shifted toward lower temperature monotonically by 37 °C per mol % Fe<sup>3+</sup> ion. Simultaneously, the phase transitions gradually changed from classical ferroelectric-to-paraelectric phase transitions into diffuse phase transitions with a weak relaxor characteristic. Purely electrostrictive responses with giant electrostrictive coefficient Q<sub>33</sub> between 0.04 and 0.05 m<sup>4</sup>/C<sup>2</sup> are observed from 25 to 100 °C for the compositions doped with 1-2 mol % Fe<sup>3+</sup> ion. The Q<sub>33</sub> of Fe<sup>3+</sup>-doped BZT-0.5BCT ceramics is almost twice the Q<sub>33</sub> of other ferroelectric ceramics. These observations suggest that the present system can be considered as a potential lead-free material for the applications in electrostrictive area and that BT-based ferroelectric ceramics would have giant electrostrictive coefficient over other ferroelectric systems.

Keyword:

diffuse phase transition doping electrostriction ferroelectric lead-free

Author Community:

  • [ 1 ] [Li Fei]Department of Materials Science and Engineering, Pennsylvania State University , University Park, Pennsylvania 16802, United States.
  • [ 2 ] [Yan Yan;Liu Gang]Faculty of Materials and Energy, Southwest University , Chongqing 400715, China.
  • [ 3 ] [Jin Li;Huo Renjie;Guo Runping;Li Fei;Wang Dawei;Tian Ye;Hu Qingyuan;Wei Xiaoyong]Electronic Materials Research Laboratory, Key Laboratory of the Ministry of Education & International Center for Dielectric Research, Xi'an Jiaotong University , Xi'an 710049, China.
  • [ 4 ] [He Zhanbing]State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing , Beijing 100083, China.

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Source :

ACS applied materials & interfaces

ISSN: 1944-8252

Year: 2016

Issue: 45

Volume: 8

Page: 31109-31119

7 . 5 0 4

JCR@2016

9 . 2 2 9

JCR@2020

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:239

JCR Journal Grade:2

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 9

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