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Abstract:
The electrostrictive effect has some advantages over the piezoelectric effect, including temperature stability and hysteresis-free character. In the present work, we report the diffuse phase transitions and electrostrictive properties in lead-free Fe<sup>3+</sup>-doped 0.5Ba(Zr<sub>0.2</sub>Ti<sub>0.8</sub>)O<sub>3</sub>-0.5(Ba<sub>0.7</sub>Ca<sub>0.3</sub>)TiO<sub>3</sub> (BZT-0.5BCT) ferroelectric ceramics. The doping concentration was set from 0.25 to 2 mol %. It is found that by introducing Fe<sup>3+</sup> ion into BZT-0.5BCT, the temperature corresponding to permittivity maximum T<sub>m</sub> was shifted toward lower temperature monotonically by 37 °C per mol % Fe<sup>3+</sup> ion. Simultaneously, the phase transitions gradually changed from classical ferroelectric-to-paraelectric phase transitions into diffuse phase transitions with a weak relaxor characteristic. Purely electrostrictive responses with giant electrostrictive coefficient Q<sub>33</sub> between 0.04 and 0.05 m<sup>4</sup>/C<sup>2</sup> are observed from 25 to 100 °C for the compositions doped with 1-2 mol % Fe<sup>3+</sup> ion. The Q<sub>33</sub> of Fe<sup>3+</sup>-doped BZT-0.5BCT ceramics is almost twice the Q<sub>33</sub> of other ferroelectric ceramics. These observations suggest that the present system can be considered as a potential lead-free material for the applications in electrostrictive area and that BT-based ferroelectric ceramics would have giant electrostrictive coefficient over other ferroelectric systems.
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ACS applied materials & interfaces
ISSN: 1944-8252
Year: 2016
Issue: 45
Volume: 8
Page: 31109-31119
7 . 5 0 4
JCR@2016
9 . 2 2 9
JCR@2020
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:239
JCR Journal Grade:2
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 0
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 9
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