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Author:

Zhang, W (Zhang, W.) | Wang, HJ (Wang, HJ.) | Jin, ZH (Jin, ZH.)

Indexed by:

SCIE Scopus EI

Abstract:

Porous silicon carbide/silicon nitride (SiC/Si3N4) composite ceramics with flexural strength of 78 MPa, fracture toughness of 1.68 MPa m(1/2), and porosity up to 63% were obtained by gel casting and two-step sintering using commercial phenolic resin as carbon source. Thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), X-ray diffraction (XRD), transmission electron microscopy (TEM), and three-point bending methods were employed to characterize and analyze the microstructure and basic mechanical performance of the porous ceramics. The polymer was proved to be an effective source that could provide free carbon for fabrication of the SiC nanoparticles by in situ reaction with Si3N4 and SiO2. Sizes of the formed SiC particles were in the range of 50-300 nm. Low green density, significant weight loss, and little shrinkage led to high porosity. High aspect ratio of beta-Si3N4, uniform porous distribution, and formation of proper amount of SiC particulates were the main reasons for good mechanical performance. However, only a limited amount of polymer additions had these beneficial effects. Excessive additions could cause agglomeration for residual carbon and inborn SiC, hence becoming fatal flaws for the materials. (C) 2004 Elsevier B.V. All rights reserved.

Keyword:

ceramics microstructure nanocomposites porosity

Author Community:

  • [ 1 ] Xian Jiaotong Univ, Sch Mat Sci & Engn, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China

Reprint Author's Address:

  • Xian Jiaotong Univ, Sch Mat Sci & Engn, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China.

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Source :

MATERIALS LETTERS

ISSN: 0167-577X

Year: 2005

Issue: 2-3

Volume: 59

Page: 250-256

1 . 2 9 9

JCR@2005

3 . 4 2 3

JCR@2020

ESI Discipline: MATERIALS SCIENCE;

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 44

SCOPUS Cited Count: 52

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 9

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