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Abstract:
Macroporous silicon nitride (Si3N4) ceramics with high strength, uniform structure and relatively high porosity were obtained by gelcasting and carbonthermal reaction in a two-step sintering technique. Microstructure and composition were investigated by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD). Open porosity, pore size distribution and basic mechanical performance were measured by Archimedes method, mercury intrusion porosimetry and three-point bending methods, respectively. SEM and TEM results revealed that pores were formed by elongated beta-Si3N4. SADP measurement proved the formation of SiC particles. The SiC granules were beneficial for the formation of high ratio elongated beta-Si3N4, and at proper amount, they also acted as reinforcement phase. Thermodynamic analysis indicated that the mechanisms of the reactions were mainly associated with liquid-solid reaction and gas-liquid reaction.
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JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
ISSN: 1005-0302
Year: 2005
Issue: 6
Volume: 21
Page: 894-898
0 . 1 7 5
JCR@2005
8 . 0 6 7
JCR@2020
ESI Discipline: MATERIALS SCIENCE;
JCR Journal Grade:2
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 11
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count: -1
Chinese Cited Count: -1
30 Days PV: 5
Affiliated Colleges: