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Author:

Xu, Congcong (Xu, Congcong.) | Su, Ran (Su, Ran.) | Wang, Zhipeng (Wang, Zhipeng.) | Wang, Yuting (Wang, Yuting.) | Zhang, Dawei (Zhang, Dawei.) | Wang, Jinkai (Wang, Jinkai.) | Bian, Jihong (Bian, Jihong.) | Wu, Chao (Wu, Chao.) | Lou, Xiaojie (Lou, Xiaojie.) (Scholars:娄晓杰) | Yang, Yaodong (Yang, Yaodong.)

Indexed by:

SCIE EI Scopus

Abstract:

Core-shell nanoparticles used as blocks to construct composite ceramics can exhibit high energy storage density, but the effects of original tunable shell thickness on the microstructures and energy storage property of finally sintered bulk ceramics has not been clarified, thus how to achieve the full potential of this technology to improve the energy storage density of ferroelectric-based ceramics remains to be solved. In this study, as precursors to fabricate bulk ceramics, BaTiO3@SiO2 core-shell nanoparticles were successfully synthesized by a wet-chemical method and they were used as models to investigate the effect of the core-shell nanostructured precursors on the energy storage property of the bulk composite ceramics. The original BaTiO3 nanoparticles coated with various homogenous SiO2 shells were acquired by controlling the concentration of tetraethyl orthosilicate (TEOS). The surface microstructure of the bulk composite ceramics observed by scanning electron microscope (SEM) revealed that the SiO2 outer shell of BaTiO3@SiO2 nanoparticles plays an important role in constructing the microstructure of the ceramics. The remodeled microstructure has a great impact on leakage current density and dielectric property, and it makes a leading contribution to the energy storage performance of ceramics. As a result, the optimum SiO2 loading range was confirmed and the maximum energy storage density obtained from BaTiO3@20 wt%SiO2 was similar to 4.799 J/cm(3) at 370 kV/cm, demonstrating that nanoscale core-shell architecture is an effective strategy to improve the energy storage performance of ferroelectric-based composite ceramics. (C) 2019 Elsevier B.V. All rights reserved.

Keyword:

BaTiO3 Composite ceramics Core-shell structure Energy storage

Author Community:

  • [ 1 ] [Xu, Congcong; Su, Ran; Wang, Zhipeng; Wang, Yuting; Bian, Jihong; Wu, Chao; Lou, Xiaojie; Yang, Yaodong] Xi An Jiao Tong Univ, Frontier Inst Sci & Technol, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China
  • [ 2 ] [Zhang, Dawei] Univ New South Wales, Sch Mat Sci & Engn, Sydney, NSW 2052, Australia
  • [ 3 ] [Wang, Jinkai] Xi An Jiao Tong Univ, Ctr Nanomat Renewable Energy CNRE, State Key Lab Elect Insulat & Power Equipment, Sch Elect Engn, Xian 710049, Peoples R China
  • [ 4 ] [Xu, Congcong]Xi An Jiao Tong Univ, Frontier Inst Sci & Technol, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China
  • [ 5 ] [Su, Ran]Xi An Jiao Tong Univ, Frontier Inst Sci & Technol, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China
  • [ 6 ] [Wang, Zhipeng]Xi An Jiao Tong Univ, Frontier Inst Sci & Technol, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China
  • [ 7 ] [Wang, Yuting]Xi An Jiao Tong Univ, Frontier Inst Sci & Technol, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China
  • [ 8 ] [Bian, Jihong]Xi An Jiao Tong Univ, Frontier Inst Sci & Technol, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China
  • [ 9 ] [Wu, Chao]Xi An Jiao Tong Univ, Frontier Inst Sci & Technol, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China
  • [ 10 ] [Lou, Xiaojie]Xi An Jiao Tong Univ, Frontier Inst Sci & Technol, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China
  • [ 11 ] [Yang, Yaodong]Xi An Jiao Tong Univ, Frontier Inst Sci & Technol, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China
  • [ 12 ] [Zhang, Dawei]Univ New South Wales, Sch Mat Sci & Engn, Sydney, NSW 2052, Australia
  • [ 13 ] [Wang, Jinkai]Xi An Jiao Tong Univ, Ctr Nanomat Renewable Energy CNRE, State Key Lab Elect Insulat & Power Equipment, Sch Elect Engn, Xian 710049, Peoples R China

Reprint Author's Address:

  • Xi An Jiao Tong Univ, Frontier Inst Sci & Technol, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China.

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Source :

JOURNAL OF ALLOYS AND COMPOUNDS

ISSN: 0925-8388

Year: 2019

Volume: 784

Page: 173-181

4 . 6 5

JCR@2019

5 . 3 1 6

JCR@2020

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:131

JCR Journal Grade:2

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 18

SCOPUS Cited Count: 39

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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