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Abstract:
Zr-substituted (Bi0.5Na0.5)(Ti1−xZrx)O3 (BNTZ) with x = 0.02–0.4 ceramics were prepared using solid-state reaction technique and their structural, dielectric and ferroelectric properties were investigated systematically. X-ray diffraction results suggest that Zr4+ ion can enter the (Bi0.5Na0.5)TiO3 (BNT) crystal lattices at a limited value and a secondary phase appears in BNTZ ceramics when the x exceeds 0.1. Temperature-dependent dielectric permittivities of BNTZ ceramics show only one dielectric peak from room temperature to 500 °C for each composition, and this dielectric peak becomes broad gradually as x increases from 0.02 to 0.4. The permittivity of x = 0.4 varies less than ±10% between room temperature and 300 °C, indicating a superior thermal stability of the permittivity. Polarization enhancement is revealed by the polarization-electric field hysteresis loops and highest ferroelectric properties are obtained in x = 0.04. The electric-field-induced strains of x = 0.04 show a monotonous increase as temperature increases from 30 °C to 150 °C. At 80 kV/cm, a high strain level of 0.268% is achieved. Our results suggest that the introduction of Zr4+ ion could effectively tailor the dielectric and ferroelectric properties of BNT ceramics and x = 0.4 composition could find potential application in high temperature capacitor devices. © 2020 Elsevier Ltd and Techna Group S.r.l.
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Ceramics International
ISSN: 0272-8842
Year: 2020
Issue: 14
Volume: 46
Page: 22889-22899
4 . 5 2 7
JCR@2020
4 . 5 2 7
JCR@2020
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:84
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 10
SCOPUS Cited Count: 18
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 12
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