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Author:

Ding, Bo (Ding, Bo.) | Cai, Zhenfei (Cai, Zhenfei.) | Ahsan, Zishan (Ahsan, Zishan.) | Ma, Yangzhou (Ma, Yangzhou.) | Zhang, Shihong (Zhang, Shihong.) | Song, Guangsheng (Song, Guangsheng.) | Yuan, Changzhou (Yuan, Changzhou.) | Yang, Weidong (Yang, Weidong.) | Wen, Cuie (Wen, Cuie.)

Indexed by:

SCIE CSCD EI Web of Science

Abstract:

Lithium batteries (LIBs) with low capacity graphite anode (similar to 372 mAh g(-1)) cannot meet the ever-growing demand for new energy electric vehicles and renewable energy storage. It is essential to replace graphite anode with higher capacity anode materials for high-energy density LIBs. Silicon (Si) is well known to be a possible alternative for graphite anode due to its highest capacity (similar to 4200 mAh g(-1)). Unfortunately, large volume change during lithiation and delithiation has prevented the Si anode from being commercialized. Metal silicides are a promising type of anode materials which can improve cycling stability via the accommodation of volume change by dispersing Si in the metal inactive/active matrix, while maintain greater capacity than graphite. Here, we present a classification of Si alloying with metals in periodic table of elements, review the available literature on metal silicide anodes to outline the progress in improving and understanding the electrochemical performance of various metal silicides, analyze the challenges that remain in using metal silicides, and offer perspectives regarding their future research and development as anode materials for commercial LIBs application.

Keyword:

Anode materials Electrochemical performance Li-ion battery Metal silicides

Author Community:

  • [ 1 ] [Ding, Bo]Anhui Univ Technol, Sch Mat Sci & Engn, Minist Educ, Key Lab Green Fabricat & Surface Technol Adv Met, Maanshan 243000, Peoples R China
  • [ 2 ] [Cai, Zhenfei]Anhui Univ Technol, Sch Mat Sci & Engn, Minist Educ, Key Lab Green Fabricat & Surface Technol Adv Met, Maanshan 243000, Peoples R China
  • [ 3 ] [Ahsan, Zishan]Anhui Univ Technol, Sch Mat Sci & Engn, Minist Educ, Key Lab Green Fabricat & Surface Technol Adv Met, Maanshan 243000, Peoples R China
  • [ 4 ] [Ma, Yangzhou]Anhui Univ Technol, Sch Mat Sci & Engn, Minist Educ, Key Lab Green Fabricat & Surface Technol Adv Met, Maanshan 243000, Peoples R China
  • [ 5 ] [Zhang, Shihong]Anhui Univ Technol, Sch Mat Sci & Engn, Minist Educ, Key Lab Green Fabricat & Surface Technol Adv Met, Maanshan 243000, Peoples R China
  • [ 6 ] [Song, Guangsheng]Anhui Univ Technol, Sch Mat Sci & Engn, Minist Educ, Key Lab Green Fabricat & Surface Technol Adv Met, Maanshan 243000, Peoples R China
  • [ 7 ] [Yuan, Changzhou]Jinan Univ, Sch Mat Sci & Engn, Jinan 250022, Peoples R China
  • [ 8 ] [Yang, Weidong]CSIRO, Future Mfg Flagship, Melbourne, Vic 3168, Australia
  • [ 9 ] [Wen, Cuie]RMIT Univ, Sch Engn, Melbourne, Vic 3001, Australia
  • [ 10 ] [Ma, Yangzhou]Xi An Jiao Tong Univ, Minist Educ, Key Lab, Elect Mat Res Lab, Xian 710049, Peoples R China

Reprint Author's Address:

  • [Ma, Yangzhou]Key Laboratory of Green Fabrication and Surface Technology of Advanced Metal Materials, Ministry of Education, School of Materials Science and Engineering, Anhui University of Technology, Maanshan; 243000, China;;[Ma, Yangzhou]Electronic Materials Research Laboratory, Key Laboratory of the Ministry of Education, Xi’an Jiaotong University, Xi’an; 710049, China;;

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Source :

ACTA METALLURGICA SINICA-ENGLISH LETTERS

ISSN: 1006-7191

Year: 2020

Issue: 3

Volume: 34

Page: 291-308

2 . 7 5 5

JCR@2020

2 . 7 5 5

JCR@2020

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:84

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 13

SCOPUS Cited Count: 25

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 6

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