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[期刊]

Anchoring of Formamidinium Lead Bromide Quantum Dots on Ti3C2Nanosheets for Efficient Photocatalytic Reduction of CO2

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Author:

Que, Meidan (Que, Meidan.) | Zhao, Yang (Zhao, Yang.) | Yang, Yawei (Yang, Yawei.) | Unfold

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SCIE EI PubMed Engineering Village

Abstract:

Metal halide perovskite with a suitable energy band structure and excellent visible-light response is a prospective photocatalyst for CO2 reduction. However, the reported inorganic halide perovskites have undesirable catalytic performances due to phase-sensitive and severe charge carrier recombination. Herein, we anchor the FAPbBr3 quantum dots (QDs) on Ti3C2 nanosheets to form a FAPbBr3/Ti3C2 composite within a Schottky heterojunction for photocatalytic CO2 reduction. Upon visible-light illumination, the FAPbBr3/Ti3C2 composite photocatalyst exhibits an appealing photocatalytic performance in the presence of deionized water. The Ti3C2 nanosheet acts as an electron acceptor to promote the rapid separation of excitons and supply specific catalytic sites. An optimal electron consumption rate of 717.18 μmol/g·h is obtained by the FAPbBr3/0.2-Ti3C2 composite, which has a 2.08-fold improvement over the pristine FAPbBr3 QDs (343.90 μmol/g·h). Meanwhile, the FAPbBr3/Ti3C2 photocatalyst also displays a superior stability during photocatalytic reaction. This work expands a new insight and platform for designing superb perovskite/MXene-based photocatalysts for CO2 reduction. © 2021 American Chemical Society.

Keyword:

Band structure Bromine compounds Carbon dioxide Charge carriers Deionized water Heterojunctions Lead compounds Light Metal halides Nanocrystals Nanosheets Perovskite Photocatalytic activity Semiconductor quantum dots

Author Community:

  • [ 1 ] [Que, Meidan]College of Materials Science and Engineering, Xi'an University of Architecture and Technology, Xi'an; 710055, China
  • [ 2 ] [Zhao, Yang]College of Materials Science and Engineering, Xi'an University of Architecture and Technology, Xi'an; 710055, China
  • [ 3 ] [Yang, Yawei]School of Electronic Science and Engineering, Xi'an Jiaotong University, Xi'an; 710049, China
  • [ 4 ] [Pan, Longkai]School of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an; 710072, China
  • [ 5 ] [Lei, Wanying]College of Materials Science and Engineering, Xi'an University of Architecture and Technology, Xi'an; 710055, China
  • [ 6 ] [Cai, Weihua]College of Materials Science and Engineering, Xi'an University of Architecture and Technology, Xi'an; 710055, China
  • [ 7 ] [Yuan, Hudie]College of Materials Science and Engineering, Xi'an University of Architecture and Technology, Xi'an; 710055, China
  • [ 8 ] [Chen, Jin]College of Materials Science and Engineering, Xi'an University of Architecture and Technology, Xi'an; 710055, China
  • [ 9 ] [Zhu, Gangqiang]School of Physics and Information Technology, Shaanxi Normal University, Xi'an; 710062, China

Reprint Author's Address:

  • [Que, Meidan]College of Materials Science and Engineering, Xi'an University of Architecture and Technology, Xi'an; 710055, China;;

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Source :

ACS Applied Materials and Interfaces

ISSN: 1944-8244

Year: 2021

Issue: 5

Volume: 13

Page: 6180-6187

9 . 2 2 9

JCR@2020

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:36

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 24

SCOPUS Cited Count: 72

30 Days PV: 8

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