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Author:

Jin, Jing (Jin, Jing.) | Ma, Chuansheng (Ma, Chuansheng.) | Hu, Guangliang (Hu, Guangliang.) | Lu, Lu (Lu, Lu.) | Liang, Zhongshuai (Liang, Zhongshuai.) | Zhao, Wanli (Zhao, Wanli.) | Liu, Yutong (Liu, Yutong.) | Ma, Chunrui (Ma, Chunrui.) | Liu, Ming (Liu, Ming.)

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Abstract:

High-performance silicon-integrated dielectric thin film capacitors with superior thermal stability are strongly attractive for application in integrated circuits and electronic devices. Here, by combining interface engineering with thermal management, lead-free 0.85BaTiO3-0.15Bi(Mg0.5Zr0.5)O3 (BT-BMZ) dielectric thin film capacitors were integrated on Si, HfO2-buffered Si (HfO2/Si), and graphene-buffered HfO2/Si (G/HfO2/Si) substrates. Benefiting from not only high-quality interface between HfO2 and Si but also the heat dissipation effect of the graphene layer, an ultra-high energy storage density up to 102 J/cm3 with an efficiency of 74.57% was obtained in BT-BMZ/G/HfO2/Si at room temperature. More importantly, the optimized capacitor exhibited an ultra-stable energy density of 52.1 J/cm3 (±10%) with high efficiency (over 70%) in a wide temperature range of -100 to 175 °C, greatly broadening the working temperature in comparison to BT-BMZ/Si (-100 to 100 °C). The present research provides a scalable strategy to enhance energy storage performance of dielectric capacitors, especially at elevated temperatures. © 2021 Author(s).

Keyword:

Barium titanate Capacitors Dielectric materials Energy storage Graphene Hafnium oxides Magnesium compounds Silicon Temperature control Thin films Zirconium compounds

Author Community:

  • [ 1 ] [Jin, Jing]School of Microelectronics, Xi'An Jiaotong University, Xi'an; 710049, China
  • [ 2 ] [Ma, Chuansheng]School of Microelectronics, Xi'An Jiaotong University, Xi'an; 710049, China
  • [ 3 ] [Hu, Guangliang]School of Microelectronics, Xi'An Jiaotong University, Xi'an; 710049, China
  • [ 4 ] [Lu, Lu]School of Microelectronics, Xi'An Jiaotong University, Xi'an; 710049, China
  • [ 5 ] [Liang, Zhongshuai]School of Microelectronics, Xi'An Jiaotong University, Xi'an; 710049, China
  • [ 6 ] [Liang, Zhongshuai]Xi'An Key Laboratory of Sustainable Energy Materials Chemistry, MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, School of Chemistry, Xi'An Jiaotong University, Xi'an; 710049, China
  • [ 7 ] [Zhao, Wanli]Science and Technology on Electro-Optical Information Security Control Laboratory, Tianjin; 300308, China
  • [ 8 ] [Liu, Yutong]Science and Technology on Electro-Optical Information Security Control Laboratory, Tianjin; 300308, China
  • [ 9 ] [Ma, Chunrui]State Key Laboratory for Mechanical Behavior of Materials, School of Materials Science and Engineering, Xi'An Jiaotong University, Xi'an; 710049, China
  • [ 10 ] [Liu, Ming]School of Microelectronics, Xi'An Jiaotong University, Xi'an; 710049, China

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Source :

Applied Physics Letters

ISSN: 0003-6951

Year: 2021

Issue: 24

Volume: 119

3 . 7 9 1

JCR@2020

ESI Discipline: PHYSICS;

ESI HC Threshold:26

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 4

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 11

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