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Abstract:
Gamma-ray induced changes occurring in ethylene-propylene-diene copolymer (EPDM) were analyzed through its complex permittivity spectra. First, four different processes, namely, instantaneous polarization, hopping of ions, segmental relaxation, and dc conduction are found to contribute to the complex permittivity. By fitting the spectra to theoretical equations, it has become clear that the instantaneous polarization and ionic hopping become active by the irradiation, indicating that generation of oxidative products and mobile ions and occurrence of chain scission are induced by gamma rays. Furthermore, since both the thermal expansion and the contribution of the segmental relaxation to the permittivity become less with an increase in dose, it is assumed that crosslinking is induced by the gamma irradiation.
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IEEE TRANSACTIONS ON DIELECTRICS AND ELECTRICAL INSULATION
ISSN: 1070-9878
Year: 2016
Issue: 6
Volume: 23
Page: 3620-3630
2 . 1 1 5
JCR@2016
2 . 9 3 1
JCR@2020
ESI Discipline: ENGINEERING;
ESI HC Threshold:128
JCR Journal Grade:2
CAS Journal Grade:4
Cited Count:
WoS CC Cited Count: 23
SCOPUS Cited Count: 34
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 4
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