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Abstract:
The reliability of piezoelectricity under thermal-cycling is an important consideration for the practical application of Pb-free piezoelectric materials. In this paper, we investigated the effect of thermal-cycling on the piezoelectricity of 0.5Ba(Zr0.2Ti0.8)O3-0.5(Ba0.7Ca0.3)TiO3 (BZT-BCT) Pb-free piezoceramic. The results show that, in BZT-BCT, the tetragonal-orthorhombic (T-O) transition causes a strong piezoelectricity degradation (∼40% reduction after 60 thermal cycles between −40 °C and 50 °C), whereas the orthorhombic-rhombohedral (O-R) transition only leads to negligible degradation during the thermal-cycling test, indicating a weak depoling effect. The comparative studies made between BZT-BCT and BaTiO3 (BT) reveal that the weak depoling effect results from the diffuseness of the O-R transition in BZT-BCT and weak domain pattern change across the transition. Our work implies that Pb-free piezoelectrics with good thermal-cycling stability can be achieved through engineering the normal ferroelectric-to-ferroelectric transition to a diffused one, which may help to design new Pb-free piezoelectric materials with good thermal-cycling stability. © 2020 Elsevier B.V.
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Source :
Journal of Alloys and Compounds
ISSN: 0925-8388
Year: 2020
Volume: 847
5 . 3 1 6
JCR@2020
5 . 3 1 6
JCR@2020
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:84
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 3
SCOPUS Cited Count: 8
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1