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Abstract:
Designing high temperature piezoelectric ceramics with large electromechanical properties is key to the actuators application in harsh environment. BiFeO3-BaTiO3 based piezoelectric ceramics are the promising candidates due to their high electromechanical properties and high Curie temperature. Here, the simple A-site single K+ doped 0.63Bi1−xKxFeO3-0.37BaTiO3 (abbreviated as 0.63B1−xKxF-0.37BT) ceramics with positive temperature dependent electromechanical properties were fabricated via conventional solid phase method. The electromechanical properties in the 0.63B1−xKxF-0.37BT ceramics are closely related to the content of K+ doping. The excellent electromechanical properties of S= 0.26% and d33*=861 pm/V under low electric field of 30 kV/cm at 105 are achieved in the 0.63B0.9975K0.0025F-0.37BT ceramic, which is conducive to their application at high temperature. Combined with the microstructure and PFM, the optimized electromechanical properties in 0.63B0.9975K0.0025F-0.37BT ceramic are mainly due to more nanodomains switching facilitated by the large grain size and local structural heterogeneity. The site engineering of A-site single ion doping is an efficient and simple strategy for BF-BT based piezoelectric ceramics to achieving excellent electromechanical properties under low electric field at high temperature. © 2021 Elsevier B.V.
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Journal of Alloys and Compounds
ISSN: 0925-8388
Year: 2021
Volume: 899
5 . 3 1 6
JCR@2020
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:36
Cited Count:
WoS CC Cited Count: 0
SCOPUS Cited Count: 7
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 0