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Abstract:
In this work, we studied the supercritical water oxidation (SCWO) of the textile sludge, the hydrothermal conversion of typical textile compounds and the corrosion properties of stainless steel 316. Moreover, the influence mechanisms of NaOH during these related processes were explored. The results show that decomposition efficiency for organic matter in liquid phase of the textile sludge was improved with the increment of reaction temperature or oxidation coefficient. However, the organic substance in solid phase can be oxidized completely in supercritical water. Serious coking occurred during the high pressure water at 250-450 degrees C for the Reactive Orange 7, while at 300 and 350 degrees C for the polyvinyl alcohol. The addition of NaOH not only accelerated the destruction of organic contaminants in the SCWO reactor, but effectively inhibited the dehydration conversion of textile compounds during the preheating process, which was favorable for the treatment system of textile sludge. The corrosion experiment results indicate that the stainless steel 316 could be competent for the body materials of the reactor and the heat exchangers. Furthermore, there was prominent enhancement of sodium hydroxide for the corrosion resistance of 316 in subcritical water. On the contrary the effect was almost none during SCWO.
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ENVIRONMENTAL TECHNOLOGY
ISSN: 0959-3330
Year: 2017
Issue: 15
Volume: 38
Page: 1949-1960
1 . 6 6 6
JCR@2017
3 . 2 4 7
JCR@2020
ESI Discipline: ENVIRONMENT/ECOLOGY;
ESI HC Threshold:162
JCR Journal Grade:3
CAS Journal Grade:4
Cited Count:
WoS CC Cited Count: 23
SCOPUS Cited Count: 26
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 16
Affiliated Colleges: