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Abstract:
Pyrochlore Bi1.5Zn1.0Nb1.5O7 (BZN) thin films deposited at 650 degrees C under an oxygen pressure of 10 Pa by pulsed laser deposition were characterized as a function of zinc amount. The zinc concentration in the thin films was varied using ceramic targets having 0-40 mol% excess zinc contents. The X-ray diffraction measurement shows that thin films have a cubic pyrochlore phase structure and a strong preferential orientation of (111) plane. The dielectric properties are investigated as functions of temperature and frequency. Dielectric constant and loss tangent of the thin films both slightly increase with the increase of Zn amount. The thin film with 40 mol% zinc exhibits a dielectric constant of 198 and a loss tangent of 0.004 at 10 kHz. The dielectric relaxation behavior has been studied by measuring the temperature dependence of dielectric properties. The characteristic temperatures (T-m) move to the high temperature with the increase of Zn and gradually approach that of BZN ceramic. Meanwhile, in a wide frequency and temperature range (1 kHz-1 MHz, -100-150 degrees C), the dielectric constant of the thin films almost keeps unchanged and shows a negative temperature coefficient. Leakage current density of the thin films with 20 mol% zinc is approximately three order magnitude lower than that of films with 0 mol% zinc at 400 kV/cm. The conduction of BZN thin films is controlled by the Schottky emission mechanism and the space-charge-limited current mechanism. (C) 2012 Elsevier B. V. All rights reserved.
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JOURNAL OF ALLOYS AND COMPOUNDS
ISSN: 0925-8388
Year: 2013
Volume: 553
Page: 8-13
2 . 7 2 6
JCR@2013
5 . 3 1 6
JCR@2020
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:292
JCR Journal Grade:2
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 17
SCOPUS Cited Count: 19
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 3